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Bridging Size Scales with Self-Assembling Supramolecular Materials

Published online by Cambridge University Press:  31 January 2011

Peter Kazmaier  and
Naveen Chopra
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Extract

The notion of micromachines made up of miniature gears and motors may seem like a fairy tale. In 1959, Richard Feynman delivered a lecture entitled “There's Plenty of Room at the Bottom,” a bold prediction of what was to come in the future, where one could fit the entire Encyclopaedia Britannica onto the head of a pin or use ions focused through a microscope lens in reverse to etch away silica to create patterns on a submicron scale. In retrospect, Feynman's hypotheses were amazingly accurate. He was describing the techniques of microlithography and the manipulation of atoms by scanning tunneling electron microscopy, methods that are commonplace today. Advances in biochemistry have revealed the enormous complexity of “simple” organisms, leading one to conclude that “micromachines” (of a complexity that a visionary giant such as Feynman had foreseen) have long been operating quite happily without any assistance from chemists!

Type
Research Article
Information
MRS Bulletin , Volume 25 , Issue 4: Supramolecular Materials , April 2000 , pp. 30 - 35
Copyright
Copyright © Materials Research Society 2000

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References

1. Feynman, R., “There's Plenty of Room at the Bottom,” presented at the Annual Meeting of the American Physical Society, California Institute of Technology, December 26, 1959.Google Scholar
2. Carroll, B.H., Higgins, G.C., and James, T.H., Introduction to Photographic Theory (John Wiley & Sons, New York, 1980).Google Scholar
3. Rose, A. and Weimer, P.K., Phys. Today 42 (1989) p. 24.CrossRefGoogle Scholar
4. Moreau, W.M., Semiconductor Lithography: Principles and Materials (Plenum Press, New York, 1988).CrossRefGoogle Scholar
5. For recent progress accounts in microelectronics, see Deal, B. and Talbot, J., Electrochem. Soc. Interface 6 (1997) p. 18; C.R. Barrett, MRS Bull. XXVIII (1993) p. 3.CrossRefGoogle Scholar
6. For an excellent review of various lithographic techniques, including soft lithography, see Xia, Y. and Whitesides, G.M., Angew. Chem., Int. Ed. Engl. 37 (1998) p. 550.3.0.CO;2-G>CrossRefGoogle Scholar
7. Blair, D., Semin. Cell Biol. 1 (1990) p. 75 and references therein.Google Scholar
8. For leading references on self-assembly, see Lindsey, J.S., New J. Chem. 15 (1991) p. 153; G.M. Whitesides, J.P. Mathias, and C.T. Seto, Science 254 (1991) p. 1312; J.-M. Lehn, Angew. Chem., Int. Ed. Engl. 29 (1990) p. 1304.Google Scholar
9. For Nobel lectures on supramolecular chemistry, see Cram, D.J., Angew. Chem., Int. Ed. Engl. 27 (1988) p. 1009; J.-M. Lehn, Angew. Chem., Int. Ed. Engl. 27 (1988) p. 89; C.J. Pedersen, Angew. Chem., Int. Ed. Engl. 27 (1988) p. 1021.CrossRefGoogle Scholar
10. Voet, D. and Voet, J.G., Biochemistry, 2nd ed. (John Wiley & Sons, New York, 1995).Google Scholar
11. Ghadiri, M.R., Granja, J.R., and Buehler, L.K., Nature 369 (1994) p. 301.CrossRefGoogle Scholar
12. Iijima, S., Nature 354 (1991) p. 56.CrossRefGoogle Scholar
13. Xie, S.S., Chang, B.H., Li, W.Z., Pan, Z.W., Sun, L.F., Mao, J.M., Chen, X.H., Qian, L.X., and Zhou, W.Y., Adv. Mater. 11 (1999) p. 1135; T.W. Ebbesen, Phys. Today 49 (1996) p. 26.3.0.CO;2-V>CrossRefGoogle Scholar
14. Baughman, R.H., Cui, C., Zakhidov, A.A., Iqbal, Z., Barisci, J.N., Spinks, G.M., Wallace, G.G., Mazzoldi, A., Rossi, D.D., Rinzler, A.G., Jaschinski, O., Roth, S., and Kertesz, M., Science 284 (1999) p. 1340.CrossRefGoogle Scholar
15. Xia, Y., Rogers, J.A., Paul, K.E., and Whitesides, G.M., Chem. Rev. 99 (1999) p. 1823 and references therein.CrossRefGoogle Scholar
16. Piner, R.D., Zhu, J., Xu, F., Hong, S., and Mirkin, C.A., Science 283 (1999) p. 661.Google Scholar
17. Collier, C.P., Wong, E.W., Belohradsky, M., Raymo, F.M., Stoddart, J.F., Kuekes, P.J., Williams, R.W., and Heath, J.R., Science 285 (1999) p. 391.CrossRefGoogle Scholar
18. For solid 2D arrays, see Bowden, N., Terfort, A., Carbeck, J., and Whitesides, G.M., Science 276 (1997) p. 223; for 3D objects, see A. Terfort, N. Bowden, and G.M. Whitesides, Nature 386 (1997) p. 162; for LED devices, see A. Terfort and G.M. Whitesides, Adv. Mater. 10 (1998) p. 470.CrossRefGoogle Scholar
19. Mirkin, C.A., Letsinger, R.L., Mucic, R.C., and Storhoff, J.J., Nature 382 (1996) p. 607; A.P. Alivisatos, K.P. Johnsson, X. Peng, T.E. Wilson, C.J. Loweth, M.P. Bruchez Jr., and P.G. Schultz, Nature 382 (1996) p. 609.CrossRefGoogle Scholar
20. Chen, Z., Govender, D., Gross, R., and Birge, R., BioSystems 35 (1995) p. 145 and references therein. For a recent overview of BR applications, see S. Thai, Proc. SPIE-Int. Soc. Opt. Eng. 3714 (1999) p. 31.CrossRefGoogle Scholar