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The Dynamics of Mobile Ions in Ionically Conducting Glasses and Other Materials

Published online by Cambridge University Press:  29 November 2013

K.L. Ngai  and
C.T. Moynihan
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Extract

The range of applications for ionically conducting materials in technology is very broad and includes batteries; fuel cells; sensors; electrochromic displays; catalysts, oxygen, and hydrogen pumps; and bionics. In most of these applications, the mobility of the ions is a determining factor for optimum performance. Examples are liquid-electrolyte and plastic Li+ ion batteries for portable electronics, solid oxide fuel cells such as the oxygen ion-conducting stabilized zirconia electrolyte for energy conversion, and exchange of different ions in oxide glasses for the fabrication of micro-optic lenses. Therefore research on the dynamics of ionic transport that clarifies the mechanisms limiting the mobility of the ions is useful. These dynamic processes are also fascinating from a basic research point of view and qualitatively follow general patterns independent of the chemical and physical structures of the materials, suggesting that some fundamental physical mechanism is at work. On a quantitative level, the ionic-transport properties depend on the structures of the materials seemingly in well-defined patterns, which can be used to advantage in choosing materials for specific applications.

Type
New Functionality in Glass
Information
MRS Bulletin , Volume 23 , Issue 11 , November 1998 , pp. 51 - 56
Copyright
Copyright © Materials Research Society 1998

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