Hostname: page-component-586b7cd67f-dlnhk Total loading time: 0 Render date: 2024-11-28T14:25:49.427Z Has data issue: false hasContentIssue false
  • English
  • Français

Interwoven polymer composites via dual-electrospinning with shape memory and self-healing properties

Part of: Polymers and Soft Matter

Published online by Cambridge University Press:  15 June 2015

Hossein Birjandi Nejad ,
Jaimee M. Robertson  and
Patrick T. Mather
Hossein Birjandi Nejad
Affiliation:
Syracuse Biomaterials Institute and Department of Biomedical and Chemical Engineering, Syracuse University, Syracuse, New York 13244, USA
Jaimee M. Robertson
Affiliation:
Syracuse Biomaterials Institute and Department of Biomedical and Chemical Engineering, Syracuse University, Syracuse, New York 13244, USA
Patrick T. Mather*
Affiliation:
Syracuse Biomaterials Institute and Department of Biomedical and Chemical Engineering, Syracuse University, Syracuse, New York 13244, USA
*
Address all correspondence to Patrick T. Mather at ptmather@syr.edu
Get access

Abstract

Material research and development is increasingly focusing on achieving specialized functionality in materials. For example, the ability to “self-heal (SH)”, or naturally repair accrued damage, is attractive because it extends the lifetime of the material by increasing resistance to damaging conditions and prolonging preservation of material properties. Additionally, shape memory (SM) materials, including SM polymers, are actively considered for their ability to change shape one or more times upon application of an external stimulus. Here, we present a polymer composite, composed of poly(vinyl acetate) (PVAc) and poly(ε-caprolactone) (PCL), exhibiting both SH and SM functionalities. In fact, the SM assists in the SH ability in a process developed by our group termed, shape memory-assisted self-healing (SMASH). The advantage of the SH composite presented here is its simple fabrication. Dual-electrospinning is used to simultaneously electrospin PVAc and PCL, achieving an interwoven polymeric composite of otherwise immiscible polymers. The dual-electrospinning method facilitates precise control of the relative weight fractions of the components, and thus allows for tuning of the material properties. Upon thermal activation, damaged PVAc–PCL composites exhibited SH under a variety of testing conditions. Furthermore, the composites exhibited impressive dual and triple SM capabilities in the dry and hydrated states, respectively. Together, the commercial availability of the components and the simplicity of preparation translate to a SMASH system that could be mass produced and used as a SH coating or alone, as a packaging material.

Type
Polymers/Soft Matter Research Letters
Information
MRS Communications , Volume 5 , Issue 2 , June 2015 , pp. 211 - 221
Copyright
Copyright © Materials Research Society 2015 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Wu, D.Y., Meure, S., and Solomon, D.: Self-healing polymeric materials: a review of recent developments. Progr. Polym. Sci. 33, 479 (2008).CrossRefGoogle Scholar
2.Kessler, M.: Self-healing: a new paradigm in materials design. Proc. Inst. Mech. Eng. G: J. Aerosp. Eng. 221, 479 (2007).CrossRefGoogle Scholar
3.Wool, R.P.: Self-healing materials: a review. Soft Matter 4, 400 (2008).Google Scholar
4.White, S.R., Sottos, N., Geubelle, P., Moore, J., Kessler, M.R., Sriram, S., Brown, E., and Viswanathan, S.: Autonomic healing of polymer composites. Nature 409, 794 (2001).Google Scholar
5.Liu, Y.-L. and Chuo, T.-W.: Self-healing polymers based on thermally reversible Diels–Alder chemistry. Polym. Chem. 4, 2194 (2013).CrossRefGoogle Scholar
6.Kessler, M., Sottos, N., and White, S.: Self-healing structural composite materials. Compos. A: Appl. Sci. Manuf. 34, 743 (2003).CrossRefGoogle Scholar
7.Lendlein, A. and Kelch, S.: Shape-memory polymers. Angew. Chem. Int. Ed. 41, 2034 (2002).3.0.CO;2-M>CrossRefGoogle ScholarPubMed
8.Mather, P.T., Luo, X., and Rousseau, I.A.: Shape memory polymer research. Annu. Rev. Mater. Res. 39, 445 (2009).Google Scholar
9.Rodriguez, E.D., Luo, X., and Mather, P.T.: Linear/network poly (ε-caprolactone) blends exhibiting shape memory assisted self-healing (SMASH). ACS Appl. Mater. Interfaces 3, 152 (2011).CrossRefGoogle ScholarPubMed
10.Luo, X. and Mather, P.T.: Shape memory assisted self-healing coating. ACS Macro Lett. 2, 152 (2013).CrossRefGoogle ScholarPubMed
11.Greiner, A. and Wendorff, J.H.: Electrospinning: a fascinating method for the preparation of ultrathin fibers. Angew. Chem. Int. Ed. 46, 5670 (2007).CrossRefGoogle ScholarPubMed
12.Subbiah, T., Bhat, G., Tock, R., Parameswaran, S., and Ramkumar, S.: Electrospinning of nanofibers. J. Appl. Polym. Sci. 96, 557 (2005).Google Scholar
13.Pham, Q.P., Sharma, U., and Mikos, A.G.: Electrospinning of polymeric nanofibers for tissue engineering applications: a review. Tissue Eng. 12, 1197 (2006).Google Scholar
14.Moghe, A. and Gupta, B.: Co-axial electrospinning for nanofiber structures: preparation and applications. Polym. Rev. 48, 353 (2008).CrossRefGoogle Scholar
15.Liu, Z.Y., Sun, D.D.L., Guo, P., and Leckie, J.O.: An efficient bicomponent TiO2/SnO2 nanofiber photocatalyst fabricated by electrospinning with a side-by-side dual spinneret method. Nano Lett. 7, 1081 (2007).Google Scholar
16.Madhugiri, S., Dalton, A., Gutierrez, J., Ferraris, J.P., and Balkus, K.J.: Electrospun MEH-PPV/SBA-15 composite nanofibers using a dual syringe method. J. Am. Chem. Soc. 125, 14531 (2003).CrossRefGoogle ScholarPubMed
17.Park, J.H. and Braun, P.V.: Coaxial electrospinning of self-healing coatings. Adv. Mater. 22, 496 (2010).Google Scholar
18.Yamaguchi, M., Ono, S., and Terano, M.: Self-repairing property of polymer network with dangling chains. Mater. Lett. 61, 1396 (2007).CrossRefGoogle Scholar
19.Ferrer-Balas, D., Maspoch, M.L., Martinez, A., and Santana, O.: On the essential work of fracture method: energy partitioning of the fracture process in iPP films. Polym. Bull. 42, 101 (1999).CrossRefGoogle Scholar
20.Koerner, H., Price, G., Pearce, N.A., Alexander, M., and Vaia, R.A.: Remotely actuated polymer nanocomposites—stress-recovery of carbon-nanotube-filled thermoplastic elastomers. Nat. Mater. 3, 115 (2004).Google Scholar
21.Ge, Q., Luo, X., Iversen, C.B., Nejad, H.B., Mather, P.T., Dunn, M.L., and Jerry Qi, H.: A finite deformation thermomechanical constitutive model for triple shape polymeric composites based on dual thermal transitions. Int. J. Solids Struct. 51, 2777 (2014).CrossRefGoogle Scholar
22.Richard-Lacroix, M. and Pellerin, C.: Molecular orientation in electrospun fibers: from mats to single fibers. Macromolecules 46, 9473 (2013).CrossRefGoogle Scholar
23.Pedicini, A. and Farris, R.J.: Mechanical behavior of electrospun polyurethane. Polymer 44, 6857 (2003).CrossRefGoogle Scholar
24.Huang, W., Yang, B., An, L., Li, C., and Chan, Y.: Water-driven programmable polyurethane shape memory polymer: demonstration and mechanism. Appl. Phys. Lett. 86, 114105 (2005).Google Scholar
25.Yang, B., Huang, W., Li, C., and Li, L.: Effects of moisture on the thermomechanical properties of a polyurethane shape memory polymer. Polymer 47, 1348 (2006).Google Scholar
26.Torbati, A.H., Mather, R.T., Reeder, J.E., and Mather, P.T.: Fabrication of a light-emitting shape memory polymeric web containing indocyanine green. J. Biomed. Mater. Res. B: Appl. Biomater. 102, 1236 (2014).Google Scholar
27.Torbati, A.H., Nejad, H.B., Ponce, M., Sutton, J.P., and Mather, P.T.: Properties of triple shape memory composites prepared via polymerization-induced phase separation. Soft Matter 10, 3112 (2014).Google Scholar
28.Nejad, H.B., Baker, R.M., and Mather, P.T.: Preparation and characterization of triple shape memory composite foams. Soft Matter 10, 8066 (2014).Google Scholar
29.Luo, X. and Mather, P.T.: Triple-shape polymeric composites (TSPCs). Adv. Funct. Mater. 20, 2649 (2010).Google Scholar
Supplementary material: PDF

Birjandi Nejad supplementary material S1

Cospin-SMASH-Supplementary-Revision Round 1

Download Birjandi Nejad supplementary material S1(PDF)
PDF 2.2 MB