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About Chemical Bonds in Misfit Layer Chalcogenides

Published online by Cambridge University Press:  15 February 2011

J. Rouxel  and
A. Meerschaut
J. Rouxel
Affiliation:
Institut des Matériaux de Nantes, UMR CNRS No 110- Universitéde Nantes, BP 32229, 2 rue de la Houssinière, 44322 NANTES Cedex 3 -, France.
A. Meerschaut
Affiliation:
Institut des Matériaux de Nantes, UMR CNRS No 110- Universitéde Nantes, BP 32229, 2 rue de la Houssinière, 44322 NANTES Cedex 3 -, France.
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Abstract

On the basis of crystal structures and electronic properties, a critical discussion of the nature of chemical bonds in misfit layered chalcogenides is given. It concerns also the various mechanisms of non-stoichiometry that are present in these incommensurate structures. Misfit chalcogenides with a LnY slab opposed to TY2 ones (T = Ti, V, Cr, Nb, Ta) appear as infinite two-dimensional intercalation compounds with an electron donation from LnY to TY2. In case of PbY or SnY slabs a more complex mechanism involving coupled substitutions in both slabs seems to prevail.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 453: Symposium R – Solid State Chemistry of Inorganic Materials , 1996 , 3
Copyright
Copyright © Materials Research Society 1997

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