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Al-Ge Phase Separation During Vapor Deposition

Published online by Cambridge University Press:  21 February 2011

C. D. Adams
Affiliation:
Department of Materials Science and Engineering, The University of Michigan, Ann Arbor, MI 48109
M. Atzmon
Affiliation:
Department of Nuclear Engineering, The University of Michigan, Ann Arbor, MI 48109.
Y.-T. Cheng
Affiliation:
General Motors Research Laboratories, Physical Chemistry Department, Warren, MI 48090–9055
D. J. Srolovitz
Affiliation:
Department of Materials Science and Engineering, The University of Michigan, Ann Arbor, MI 48109
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Abstract

The phase- and grain microstructure and surface morphology of Al-Ge films formed by electron beam co-deposition have been studied as a function of the deposition temperature. X-ray diffraction, scanning- and transmission electron microscopy with x-ray fluorescence analysis were used to characterize the films. At room temperature and above, crystalline, phase separated films are obtained. The phase dimensions and surface roughness were observed to increase with the deposition temperature and the dependence yields activation energies for atomic migration consistent with a surface diffusion mechanism. The surface roughness is observed to reflect the microstructure under the surface.

Type
Research Article
Copyright
Copyright © Materials Research Society 1990

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References

1. Movchan, B. A. and Demchishin, A. V., Phys. Met. Metallogr. 28, 83 (1969).Google Scholar
2. Mayer, J. W. and Lau, S. S., Electronic Materials Science: for Integrated Circuits in Si and GaAs (MacMillan, New York 1990).Google Scholar
3. Deutscher, G., Rappaport, M., and Ovadiahu, Z., Sol. St. Comm. 28, 593 (1978).Google Scholar
4. Binary Alloy Phase Diagrams, ed. Massalski, T. B., (ASM, Metals Park 1986), p. 116.Google Scholar
5. Herd, S. R., Chaudhari, P., and Brodsky, M. H., J. Non-Cryst. Sol. 7, 309 (1972).Google Scholar
6. Hultman, L., Robertson, A., Hentzell, H. T. G., and Hengstrom, I., J. Appl. Phys. 62, 3647 (1987).Google Scholar
7. Vollin, T. E., and Ballufi, R. W., Phys. Stat. Solidi 25, 163, (1968).Google Scholar
8. Burke, J., and Ramachandran, T. R., Met. Trans. 3 No. 1, 147–55, (1972).Google Scholar
9. Widmer, H. and Gunther-Mohr, G. R., Helv. Phys. Acta., 34, 635, (1961).Google Scholar
10. Cottrell, A., An Introduction to Metallurgy, (Arnold, London 1975), p. 340.Google Scholar
11. Howard, R. T. and Cowen, M., Trans. AIME 172, 413 (1947).Google Scholar
12. Peterson, N. L. and Rothman, S. J., Phys. Rev. B1, 3264, (1970).Google Scholar
13. Pines, B. Ya and Zyman, Z. Z., Fiz. Metal. Metalloved 25, 840 (1968).Google Scholar
14. Saunders, N. and Miodownik, P., J. Mat. Sc. 22, 629 (1987).Google Scholar
15. Unruh, K. M., Meng, W. J., and Johnson, W. L. in Layered Structures, Epitaxy, and Interfaces, eds. Gibson, J. M. and Dawson, L. R. (MRS, Pittsburgh, PA 1985), p. 551.Google Scholar