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Alkaline Cements of Waste Glass and Metakaolin, Strength as a Function of the Chemical Composition

Published online by Cambridge University Press:  11 November 2013

D. E. Ortega-Zavala ,
Alexander Gorokhovsky  and
J. I. Escalante-García
D. E. Ortega-Zavala
Affiliation:
Centro de Investigación y de Estudios Avanzados del IPN (Unidad Saltillo), Av. Industria Metalúrgica No. 1062 Parque Industrial, Ramos Arizpe, Coahuila, C.P. 25900, México, Tel.+52 (844)438-9600 fax 4389610, Email: esmeralda.ortega@cinvestav.edu.mxivan.escalante@cinvestav.edu.mx
Alexander Gorokhovsky
Affiliation:
Department of Chemistry, Saratov State Technical University, 77 Politekhnicheskaya str., Saratov, 410054, Russia.
J. I. Escalante-García
Affiliation:
Centro de Investigación y de Estudios Avanzados del IPN (Unidad Saltillo), Av. Industria Metalúrgica No. 1062 Parque Industrial, Ramos Arizpe, Coahuila, C.P. 25900, México, Tel.+52 (844)438-9600 fax 4389610, Email: esmeralda.ortega@cinvestav.edu.mxivan.escalante@cinvestav.edu.mx
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Abstract

Pastes of waste glass (WG) and metakaolin (MK) were prepared by chemical activation with sodium silicate solutions of modulus Ms = 0.5, 0.75, 1 and 1.25 adjusted with sodium hydroxide. An experimental design was carried out using the Taguchi method. The compressive strength (CS) was followed for up to 120 days and then 4 selected formulations of the higher CS were further characterized by X-ray diffraction and scanning electron microscopy. The results showed that the CS depends on the experimental conditions of %WG, %Na2O and Ms and showed a maximum of 70 MPa after 120 days for the paste with 100%WG (%wt.), 8% Na2O and Ms=1.25; while a Portland cement specimen cured at 20°C reached 43MPa. The WG is more reactive than the MK under less alkaline conditions. The features of the microstructures varied notably with the %WG; however all showed relative dense matrices of reaction products, in agreement with the CS attained.

Keywords

compositewaste managementadditives
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1612: Symposium 4B – Durability of Concrete Structures , 2013 , imrc2013-s4b-p033
Copyright
Copyright © Materials Research Society 2013 

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References

REFERENCES

R. Roskovic, D. Bjegovic, Cement and Concrete Research 35, 974–978 (2005).CrossRefGoogle Scholar
PURDON, A.,.J.Soc.Chem.Ind 59, 191–202 (1940).Google Scholar
Davidovits, J., Journal of Materials Education 16, 91–138 (1994).Google Scholar
Zhang, S., Gong, K., J. Lu., Materials Letters 58 1292 – 1296 (2004).CrossRefGoogle Scholar
J.D. Kenneth Mackenzie in What are these things called geopolymers? A physic-chemical perspective, edited by eds N. P. Bansal, J.P. Singh, W. M. Kriven and H. Schneider. (Advances in Ceramic Matrix Composites. IX, 2003) pp. 175–185.Google Scholar
Shi, C., Zheng, K., A review on the use of waste glasses in the production of cement and concrete, Conservation and recycling, 2007, Vol. 52. Ed. Elsevier B.V.CrossRefGoogle Scholar
Schwarz, N., Neithalath, N., Cement and Concrete Research 38, 429–436 (2008).CrossRefGoogle Scholar
Shvarzman, A., Kovler, K., Grader, G.S., Cement and Concrete Research 33, 405–416 (2003).Google Scholar
NMX-C-056-ONNCCE-2006, Annual book of NMX standards, Industria de la construcción, México DF (1997).Google Scholar
Escalante-García, J.I, Sharp, J.H., Advances in Cement Research 12, 121–130 (2000).Google Scholar
Grutzeck, M, Kwan, S, DiCola, M, Cem Concr Res 34, 949–955 (2004).CrossRefGoogle Scholar
Espinoza, L.J., Escalante-Garcia, J. I., NEXO Revista científica 24, 92–103 (2011).CrossRefGoogle Scholar