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Bulk Growth Of Silicon Carbide Crystals: Analysis Of Growth Rate And Crystal Quality

Published online by Cambridge University Press:  10 February 2011

D. Hofmann
Affiliation:
Materials Science Dept. 6, University of Erlangen-Nürnberg, Martensstr. 7, D-91058 Erlangen, Germany
R. Eckstein
Affiliation:
SiCrystal AG, Heinrich-Hertz-Platz 2, D-92275 Eschenfelden, Germany
L. Kadinski
Affiliation:
Fluid Mechanics Dept., University of Erlangen-Ntirnberg, Cauerstr. 4, D-91058 Erlangen, Germany
M. Kölbl
Affiliation:
SiCrystal AG, Heinrich-Hertz-Platz 2, D-92275 Eschenfelden, Germany
M. Müller
Affiliation:
Materials Science Dept. 6, University of Erlangen-Nürnberg, Martensstr. 7, D-91058 Erlangen, Germany
St. G. Müller
Affiliation:
Materials Science Dept. 6, University of Erlangen-Nürnberg, Martensstr. 7, D-91058 Erlangen, Germany
E. Schmitt
Affiliation:
SiCrystal AG, Heinrich-Hertz-Platz 2, D-92275 Eschenfelden, Germany
A. Weber
Affiliation:
SiCrystal AG, Heinrich-Hertz-Platz 2, D-92275 Eschenfelden, Germany
A. Winnacker
Affiliation:
Materials Science Dept. 6, University of Erlangen-Nürnberg, Martensstr. 7, D-91058 Erlangen, Germany
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Abstract

The process conditions during SiC bulk crystal growth by physical vapor transport (PVT) are studied both theoretically and experimentally focussing on the magnitude of achievable growth rates V and possible correlations with defect formation. An increase of micropipe density with crystallization rate is observed. Growth parameters determining V are identified allowing a general non-dimensional representation of the dependencies of growth rate from kinetics, mass transport and heat transfer. It can be shown that at conventional process conditions of SiC growth by sublimation in graphite environment (5 mbar ≤p≤ 100 mbar, 2400K ≤T≤ 2600K) growth is limited by diffusion and kinetics for very short crystal lengths L and by heat transfer for geometries L> 1 mm. Including possible destabilizing effects due to constitutional supercooling an augmentation of V without deteriorating crystal quality should be conducted by stochiometry control for supression of graphitization and control of the thermal field tailoring the axial heat transfer with process time. Finally SiC growth from the liquid phase is introduced to promise a growth technique for specific SiC material as, in contrast to PVT growth, the closing of micropipes is demonstrated to be feasible.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

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References

REFERENCES

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