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Calcium Phosphate Coating on Titanium Plates by Electrodeposition

Published online by Cambridge University Press:  17 March 2011

Masahiko Ishikawa ,
Kouji Nishikawa ,
Kensuke Kuroda ,
Ichino Ryoichi ,
Masazumi Okido  and
Osamu Takai
Masahiko Ishikawa
Affiliation:
Nagoya University, CIRSE, Furo-cho, Chikusa-ku, Nagoya, 464-8603, JAPAN
Kouji Nishikawa
Affiliation:
Nagoya University, CIRSE, Furo-cho, Chikusa-ku, Nagoya, 464-8603, JAPAN
Kensuke Kuroda
Affiliation:
Nagoya University, CIRSE, Furo-cho, Chikusa-ku, Nagoya, 464-8603, JAPAN
Ichino Ryoichi
Affiliation:
Nagoya University, CIRSE, Furo-cho, Chikusa-ku, Nagoya, 464-8603, JAPAN
Masazumi Okido
Affiliation:
Nagoya University, CIRSE, Furo-cho, Chikusa-ku, Nagoya, 464-8603, JAPAN
Osamu Takai
Affiliation:
Nagoya University, CIRSE, Furo-cho, Chikusa-ku, Nagoya, 464-8603, JAPAN
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Abstract

Calcium phosphate films were deposited on titanium electrodes cathodically from CaCl2·2H2O and Ca(H2PO4)2 · H2O aqueous solutions. In this study, H2O2 addition into electrolytes was applied to enhance the electrochemical process at the solution/electrode at a smaller cathodic potential than no H2O2 addition. Deposited films were analyzed by scanning electron microscopy (SEM) observation and X-ray diffraction (XRD). Cathodic current of the Ti electrode decreased once and increased in the solution with H2O2. It shows a cathodic current peak at c.a. 25 min in the case of potentiostatic condition at - 0.756 V (vs. Ag - AgCl, sat. KCl). The calcium phosphate film grows mainly with the decrease in current after the cathodic peak. The characteristics for the electrodeposited film such as crystal morphology depends on cathodic potential, solution pH, deposition temperature and amount of H2O2 addition. Dense calcium phosphate film composed of relatively good crystalline was obtained at pH 5.5 and – 0.756 V. Film adhesion on Ti appeared to be strong by peeling test. At larger cathodic potential of – 1.156 V, the film coverage on titanium plates was smaller and film adhesion worsened. Larger cathodic polarization of more than – 1.556 V was necessary to reduce water in case without H2O2 addition.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 711: Symposia FF/GG/HH – Advanced Biomaterials--Characterization, Tissue Engineering and Complexity , 2001 , HH3.16.1
Copyright
Copyright © Materials Research Society 2002

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References

REFERENCES

1. Hara, T., Hayashi, K., Nakashima, Y., Kanemaru, T. and Iwamoto, Y., J. Bone and Joint Surgery B 81 (4), 705 (1999).Google Scholar
2. Chou, L., Marek, B., and Wagner, W. R., Biomater. 20 (10), 977 (1999).Google Scholar
3. Feng, C. F., Khor, K. A., Liu, E. J., and Cheang, P., Scripta Materialia 42 (1), 103 (1999).Google Scholar
4. Cheang, P., Khor, K. A., Teoh, L. and Tam, S. C., Biomater. 17 (19), 1901 (1996).Google Scholar
5. Zhitomirsky, I. and Gal-Or, L., J. Mater. Sci., Mater. Med. 8 (4), 213 (1997).Google Scholar
6. Ishikawa, M., Zhu, P. X., Seo, W. S. and Koumoto, K., J. Ceram. Soc. Japan 108, 714 (2000).Google Scholar
7. Okido, M., Kuroda, K., Ichino, R. and Takai, O., Int. Symp. on “Soft Solution-Processing,” (SSP-2000), Dec. 11-13, 2000, Tokyo, Japan, to be published in a special issue of Solid State Ionics.Google Scholar
8. Zhao, Z., Kondo, Y., Ichino, R. and Okido, M., in submission to J. Mater. Sci., Mater. Med. Google Scholar
9. Schmets, J., Muylder, J. V. and Pourbaix, M., “Titanium,” Atlas of Electrochemical Equilibria in Aqueous Solutions, ed. Pourvaix, M. (NACE International Cebelcor, 1974) pp.213–222.Google Scholar
10. Ohtsuki, C., Kokubo, T. and Yamamuro, T., J. Non-crystalline Solids 143, 84 (1992).Google Scholar
11. Lin, H., Seo, W. S., Kuwabara, K. and Koumoto, K., J. Ceram. Soc. Japan 104, 91 (1996).Google Scholar
12. Li, P., Ohtsuki, C., Kokubo, T., Nakanishi, K. and Soga, N., J. Am. Ceram. Soc. 75, 2094 (1992).Google Scholar