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Capacitance-Voltage Characterization of Pulsed Plasma Polymerized Allylamine Dielectrics

Published online by Cambridge University Press:  11 February 2011

Yifan Xu
Affiliation:
Department of Electrical Engineering, The Ohio State University, Columbus, OH 43210, USA
Paul Berger
Affiliation:
Department of Electrical Engineering, The Ohio State University, Columbus, OH 43210, USA Department of Physics, The Ohio State University, Columbus, OH 43210, USA
Jai Cho
Affiliation:
Department of Chemistry and Biochemistry, University of Texas, Arlington, TX 76019, USA
Richard B. Timmons
Affiliation:
Department of Chemistry and Biochemistry, University of Texas, Arlington, TX 76019, USA
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Abstract

Polyallylamine films, deposited on Si wafers by radio frequency (RF) pulsed plasma polymerization (PPP), were employed as insulating layers of metal-insulator-semiconductor (MIS) capacitors. The insulating polymer films were deposited at substrate temperatures of 25°C and 100°C. Multiple frequency capacitance-voltage (C-V) measurements indicated that an in-situ heat treatment during film deposition increased the insulator dielectric constant. The dielectric constant, calculated from the C-V data, rose from 3.03 for samples with no heat treatment to 3.55 for samples with an in-situ heat treatment. For both sample sets, the I-V data demonstrate a low leakage current value (<20fA) up to 100V with an area of 0.0307 mm2, resulting in a current density of <0.65 pA/mm2. Hysteresis in the C-V curves with differing sweep directions was more pronounced for in-situ heat-treated samples indicative of positive mobile ions.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

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References

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