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Chemoical Vapor Deposotdoo of Tungsten and Molybdenum Folms From m(η3–C3H5)4 (M=Mo, W)

Published online by Cambridge University Press:  15 February 2011

Rein U. Kirss
Affiliation:
Northeastern University, Department of Chemistry, Boston, MA 02115
Jian Chen
Affiliation:
Northeastern University, Department of Chemistry, Boston, MA 02115
Robert B. Hallock
Affiliation:
Northeastern University, Department of Chemistry, Boston, MA 02115
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Abstract

Chemical vapor deposition using tetra(allyl) tungsten and molybdenum precursors yielded amorphous tungsten and molybdenum carbide films on pyrex substrates. The films were characterized by Auger, ESCA, SEM, XRD and resistivity measurements. Volatile pyrolysis products consisted primarily of propene, C3H6.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

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References

1. a. Kaesz, H. D., Williams, R. S., Hicks, R. F., Zink, J. I.,Chen, Y-J., Muller, H-J., Xue, Z., Xu, D., Shuh, D. K., and Kim, Y. K., New J. Chem., 14, 527 1990. b. H. D. Kaesz, R. S. Williams, R. F. Hicks, Y-J. Chen, Z. Xue, D. Xu, D. K. Shuh, and H. Thridandam, in Chemical Perspectives of Microelectronic Materials edited by M. E. Gross, J. Jasinski, and J. T. Yates (Mater. Res. Soc. Proc. 131, Pittsburgh, PA 1989) p. 395.Google Scholar
2. Green, M. L. and Levy, R. L., , R. A., J. Metals June, 83 (1985).Google Scholar
3. a. Sherman, A., “Chemical Vapor Deposition for Microelectronics”, (Noyes Publications, Park Ridge, N. J., 1987). b. G. A. Prinz, Phys. Rev. Lett., 54, 1051 (1985). c. J. R. Creighton, J. Electrochem. Soc., 136, 271 (1989)., d. P. I. Lee, J. Cronin, and C. Kaanta, 136, 2108 (1989).Google Scholar
4. a. Diem, M., Fisk, M., and Goldman, J., Thin Solid Films, 107, 39 (1983). b. G. J. Vogt, J. Vac. Sci. Technol., 20, 1336 (1982). c. I. M. Watson, J. A. Connor, and R. Whyman, Polyhedron, 8, 1794 (1989). d. N. S. Gluck, G. J. Wolga, C. E. Bartosch, W. Ho, and Z. Ying, Appl. Phys. Lett., 61, 998 (1987).Google Scholar
5. For a recent review of organometallic precursors for CVD see Girolami, G. S., and Gozum, J. E., , J. E. in Chemical Vapor Deposition of Refractory Metals and Ceramics, edited by Besmann, T. M. and Gallois, B. M. (Mater. Res. Soc. Proc. 168, Pittsburgh, PA, 1990) p. 319.Google Scholar
6. a. Gozum, J. E., Pollina, D. A., Jensen, J. A., and Girolami, G. S., J. Am. Chem. Soc., 110, 2688 (1988). b. D. C. Smith, S. G. Pattillo,N. E. Elliott, T. G. Zocco, C. J. Burns, J. R. Laia, and A. P. Sattelberger, in Chemical Vaoor Deposition of Refractory Metals and Ceramics. edited by T. M. Besmann and B. M. Gallois (Mater. Res. Soc. Proc. 168, Pittsburgh, PA, 1990) p. 369.Google Scholar
7. Oberkirch, W., PhD thesis, Techn. Hochschule, Aachen., 1963.Google Scholar
8. Benn, a. R., Brock, T. H., Dias, M. C. F. B., Jolly, P. W., Rufinska, A., Schroth, G., Seevogel, K., and Wassmuth, B., Polyhedron, 9, 11 (1990). b. F. A. Cotton, and J. R. Pipal, J. Am. Chem. Soc., 93, 5441 (1971).Google Scholar
9. Xue, Z., Caulton, K. G., and Chisholm, M. H., Chem. Mater., 3,. 384 (1991).Google Scholar
10. Schwarzkopf, P., and Kieffer, R., “Refractory Hard Metals” (Macmillan Co., New York, 1953.)Google Scholar
11. Colton, R. L., and Rabalais, J. W., Inorg. Chem., 15, 236 (1976).Google Scholar
12. Wheeler, D. R., and Brainard, W. A., J. Vac. Sci. Technol., 15, 24 (1978).Google Scholar
13. Ramquist, L., Ekstig, B., Kallne, E., Norelund, E., and Manne, R., J. Phys. Chem. Solids 30, 1849 (1969).Google Scholar
14. Crawford, R. J., Hamelin, J., and Strehlke, B., J. Am. Chem. Soc., 93, 3810 (1971).Google Scholar
15. Klein, R., and Kelley, R. D., J. Phys. Chem., 79, 1780 (1975).Google Scholar
16. Korenstein, R., Hoke, W. E., Lemonias, P. J., Higa, K. T., and Harris, D. C., J. Appl. Phys. 62, 4929 (1987).Google Scholar
17. Kirss, R. U., Brown, D. W., Higa, K. T., and Gedridge, R. W. Jr., Organometallics, 10 3589 (1991).Google Scholar
18. Patnaik, S., Jensen, K. F., and Giapis, K. P., J. Cryst. Growth, 107, 390 (1991).Google Scholar
19. Martin, G., Ropero, M., and Avila, R., Phosphorous and Sulfur, 13, 213 (1982).Google Scholar
20. Gibson, V. C., Parkin, G., and Bercaw, J. E., Organometallics, 10, 220 (1991).Google Scholar
21. Bruce, M. I., Chem. Rev., 91, 197 (1991), and references therein.Google Scholar
22. Davis, R., and Kane-Maguire, L. A. P, in Comprehrensive Organometallic Chemistry Volume 3, edited by Wilkinson, G., Stone, F.G.A., and Abel, E.W., (Pergamon Press, NY 1982), Chapt. 29.2 and references therein.Google Scholar