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The Defect Structures of Fe9S10

Published online by Cambridge University Press:  21 February 2011

Thao A. Nguyen
Affiliation:
Department of Materials Science and EngineeringMassachusetts Institute of TechnologyCambridge, MA 02139, USA
Linn W. Hobbs
Affiliation:
Department of Materials Science and EngineeringMassachusetts Institute of TechnologyCambridge, MA 02139, USA
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Abstract

The defect structures of Fe9S10 have been studied by high-resolution transmission electron microscopy. Lattice images of the 3C and 4C superstructures and at least one other phase, which has not been previously reported, were observed. It has been found that the 4C superstructure transforms into the 3C superstructure rather than the MC phase as previously suggested. Intrinsic stacking faults in the sulfur sublattice and two different types of vacancy-ordering antiphase domains were also observed. Evidence from optical diffratograms of areas containing these defects suggests that complex features in the electron diffraction pattern may be artifactual.

Type
Research Article
Copyright
Copyright © Materials Research Society 2006

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References

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