Hostname: page-component-5c6d5d7d68-vt8vv Total loading time: 0.001 Render date: 2024-08-22T05:36:42.237Z Has data issue: false hasContentIssue false

Dielectric Constant of Sodium Silicate Glasses in Relation to Their Chemical Structure

Published online by Cambridge University Press:  10 February 2011

C. H. Hsieh
Affiliation:
Department of Materials Science and Engineering, Lehigh University, Bethlehem, PA 18015
H. Jain
Affiliation:
Department of Materials Science and Engineering, Lehigh University, Bethlehem, PA 18015
Get access

Abstract

The chemical structure of a series of aluminum substituted sodium trisilicate glasses is determined by x-ray photoelectron spectroscopy. It reveals a significant change of the chemical structure around the sodium cations and oxygen anions with the addition of aluminum. A microscopic model is developed to understand the composition dependence of the dielectric constant of these glasses in terms of the changes of chemical structure.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Jain, H. and Hsieh, C.H., in: Diffusion in Amorphous Materials, edited by Jain, H. and Gupta, D. (The Minerals, Metals & Materials Society, Warrendale, 1994) p. 63.Google Scholar
[2] Jain, H. and Huang, W.C., J. Non-Cryst. Solids 172, 1334 (1994).Google Scholar
[3] Hsieh, C.H., Jain, H., Miller, A.C. and Kamitsos, E.I., J. Non-Cryst. Solids 168, 247 (1994).Google Scholar
[4] Hsieh, C.H. and Jain, H., J. Non-Cryst. Solids 183, 1 (1995).Google Scholar
[5] Jain, H., in: Experimental Techniques of Glass Science, edited by Simmons, C.J. and El-Bayoumi, O.H. (The American Ceramic Society, Westerville, 1993), ch. 12, p. 433.Google Scholar
[6] Hsieh, C.H., Jain, H. and Kamitsos, E.I., “Correlation between dielectric constant and chemical structure of sodium silicate glasses,” submitted to J. Appl. Phys.Google Scholar
[7] McKeown, D.A., Waychunas, G.A. and Brown, G.E., Jr., J. Non-Cryst. Solids 74, 325 (1985).Google Scholar
[8] Zirl, D.M. and Garofalini, S.H., J. Am. Ceram. Soc. 73, 2848 (1990).Google Scholar
[9] Cao, Y. and Cormack, A.N., in: Diffusion in Amorphous Materials, edited by Jain, H. and Gupta, D. (The Minerals, Metals & Materials Society, Warrendale, PA, 1994), p. 137.Google Scholar
[10] Schroeder, J., J. Non-Cryst. Solids 40, 549 (1980).Google Scholar
[11] Agrawal, G.G., Sharma, H.P. and Shanker, J., J. Phys. Chem. Solids 38, 815 (1977).Google Scholar
[12] Varshneya, A.K., Fundamentals of Inorganic Glasses (Academic Press, San Diego, CA, 1994) ch. 19, p. 455.Google Scholar
[13] Kamitsos, E.I., Kapoutsis, J.A., Jain, H. and Hsieh, C.H., J. Non-Cryst. Solids 171, 31 (1994).Google Scholar