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Diffusion of Cesium in Sodium Borosilicate Glasses for Nuclear Waste Immobilisation

Published online by Cambridge University Press:  21 February 2011

E.G.F. Sengersi ,
F.J.J.G. Janssen  and
H. de Waal
E.G.F. Sengersi
Affiliation:
N.V. KEMA, R&D division, Chemical Research Department, P.O. Box 9035, 6800 ET Arnhem, The Netherlands
F.J.J.G. Janssen
Affiliation:
N.V. KEMA, R&D division, Chemical Research Department, P.O. Box 9035, 6800 ET Arnhem, The Netherlands
H. de Waal
Affiliation:
TNO Institute of Applied Physics - Glass Technology Department, P.O. Box 513, 5600 MB Eindhoven, The Netherlands
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Abstract

Diffusion of cesium in borosilicate glass for high-level radioactive waste is discussed. For this purpose model glasses with non-radioactive elements are being made, in accordance with the specifications of the reprocessing plants, from which concentration couples are composed. A concentration couple consists of two cylinders of borosilicate glass which contain different amounts of cesium. After heat treatment the couples are studied by means of scanning electron microscopy and X-Ray microanalysis. The model study will provide a basis for predictions of the containment achieved over a longer period of time.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 176: Symposium U – Scientific Basis for Nuclear Waste Management XIII , 1989 , 441
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

1. Kahl, L., PhD thesis, D83, University of Berlin 1974.Google Scholar
2. Boulos, E.N., DePaula, R.P., EI-Bayoumi, O.H., Lagakos, N., Macedo, P.C., Moynihan, C.T., Rekhson, S.M., J. Amer. Ceram. Soc., 63, 496–501 (1980).Google Scholar
3. Shewmon, P., Diffusion in Solids, 1st ed. (McGraw Hill Book Company, New York, 1963), 1–37.Google Scholar
4. Moser, R., Schaeffer, H.A., Tomandl, G., Glastechn.Ber., 56K, 492–497 (1983).Google Scholar
5. Dyment, F., Matzke, H.j. and Toscano, E., J. Non-Cryst. Solids, 93, 22 (1987).Google Scholar
6. Kahl, L., and Schiewer, E., Atomwirtschaft, Aug/Sept. 434–425 (1971)Google Scholar
7. Ralkova, J., Saidl, J., Kernenergie, 10, 161–164 (1967).Google Scholar
8. Matzke, H.j., Toscano, E., and Linker, G., Nucl. Instr. and Meth. B32, 508–511 (1988).Google Scholar
9. Yamashita, M., Terai, R., and Wakabayashi, H., J. Non-Cryst. Solids, 79, 213–216 (1986).Google Scholar
10. Carslaw, H.S., Jaeger, J.C., Conduction of Heat in Solids, 2nd ed.(Oxford University Press, Fair Lawn, N.J., 1959).Google Scholar
11. Dunn, T., J. Non-Cryst. Solids, 92, 1–10 (1987).Google Scholar