Hostname: page-component-5c6d5d7d68-wp2c8 Total loading time: 0 Render date: 2024-08-15T04:11:20.604Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and characterization of new materials with pyrrole units and their semiconductor behavior

Published online by Cambridge University Press:  05 July 2016

Olivia Monroy ,
Lioudmila Fomina  and
Roberto Salcedo
Olivia Monroy
Affiliation:
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior s/n. C.U. A. Postal 70-360, Delegación Coyoacán, C.P. 04510. México D.F. México
Lioudmila Fomina
Affiliation:
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior s/n. C.U. A. Postal 70-360, Delegación Coyoacán, C.P. 04510. México D.F. México
Roberto Salcedo
Affiliation:
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior s/n. C.U. A. Postal 70-360, Delegación Coyoacán, C.P. 04510. México D.F. México
Get access

Abstract

New organic materials with semiconductor behavior were prepared from diphenyldiacetylene and aromatic amines with withdrawing groups by Reisch-Schulte reaction and characterized by IR, RMN spectroscopy. The obtained materials share the property of having electron withdrawing groups joint to the attached aromatic ring, it seems this feature accounts in large fashion to improve the semiconducting behavior of this kind of substances, this topic was studied by means theoretical calculations and the results are also discussed. The calculations were carried out by means the Gaussian09 software and all the involved species were geometrically optimized.

Keywords

Chemical synthesisMacromolecular structureSemiconductor
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1819: Symposium 4D – New Trends in Polymer Chemistry and Characterization , 2016 , imrc2015s4d-p035
Copyright
Copyright © Materials Research Society 2016 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Brédas, J.L., Beljonne, D., Coropceanu, V., Cornil, J., Chem. Rev. 104, 4971 (2004).CrossRefGoogle Scholar
a) Salzner, U., Lagowski, J.B., Pickup, P.G., Poirier, R.A., J. Org. Chem. 64, 7419 (1999). b) R. Salcedo, J. Mol. Model. 13, 1027 (2007).CrossRefGoogle Scholar
Salzner, U., Synth. Metal. 101, 482 (1999).CrossRefGoogle Scholar
Schulte, K.E., Reisch, J., Walker, H., Chem. Ber. 98, 98(1965).CrossRefGoogle Scholar
Huerta, G., Fomina, L., Rumsh, L., Zolotukhin, M.G., Polymer Bulletin 57, 433 (2006).CrossRefGoogle Scholar
Becke, A.D., Phys. Rev. 38, 3098 (1988).CrossRefGoogle Scholar
Perdew, J.P., Wang, Y., Phys. Rev. B 45, 13244 (1992).CrossRefGoogle Scholar
a). Wu, C.J., Yang, L.H., Fried, L.E., Quenneville, J., Martinez, T.J., Phys. Rev. B 67, Art. No. 235101 (2003). b). Ch.W. Bauschlicher, J.W. Lawson, A. Ricca, Y.Xue, M.A. Ratner, Chem Phys. Lett. 388, 427 (2004).Google Scholar
Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseira, G.E., Robb, M.A., Cheeseman, J.R., Zakrzewski, V.G. Jr. Montgomery, J.A., Stratmann, R.E., Burant, J.C., Dapprich, S., Millam, J.M., Daniels, A.D., Kudin, K.N., Strain, M.C., Farkas, O., Tomasi, J., Barone, V., Cossi, M., Cammi, R., Menucci, B., Pomelli, C., Adamo, C., Clifford, S., Ochterski, J., Petersson, G.A., Ayala, P.Y., Morokuma, K., Malick, D.K., Rabuck, A.D., Raghavachari, K., Foresman, J.B., Cioslowski, J., Ortiz, J.V., Stefanov, B.B., Liu, G., Liashenko, A., Piskorz, P., Komaromi, I., Gomperts, R., Martin, L.R., Fox, D.J., Keith, T., Al-Laham, M.A., Peng, C.Y., Nanayakkara, A., Gonzalez, C., Challacombe, M., Gill, P.M.W., Johnson, B.G., Chen, W., Wong, M.W., Andres, J.L., Head-Gordon, M., Replogle, E.S., Pople, J.A., Gaussian98, Gaussian Inc., Pittsburgh, PA (1998).Google Scholar