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Doped Amorphous SiC, Mixed Carbide and Oxycarbide Thin Films by a Liquid Route

Published online by Cambridge University Press:  26 February 2011

C-J Chu
Affiliation:
Department of Material Science and Engineering, University of California, Los Angeles, CA90024
E. Liimatta
Affiliation:
Department of Material Science and Engineering, University of California, Los Angeles, CA90024
J. D. Mackenzie
Affiliation:
Department of Material Science and Engineering, University of California, Los Angeles, CA90024
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Abstract

A new family of disordered materials called amorphous covalent ceramics (ACC) has been obtained by pyrolysis of metal-organic polymers. The transformation from polycarbosilane to amorphous and microcrystalline SiC has been studied. New a-SiC:H thin films have also been prepared by the polymer solution. Electrical and optical properties of this new a-SiC have studied. Amorphous binary carbide and oxycarbide have also been prepared by crosslinking polycarbosilane and metal alkoxides. The p-n control of this new a-SiC:H has been achieved, which also lead to the possible device applications.

Type
Research Article
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCE

1. Walker, B.E., Rice, R.W., Becher, P.F., Bender, B.A. and Coblenz, W.S., Bull. Am. Ceram. Soc. 62, 916 (1983)Google Scholar
2. Yajima, S., Hayashi, J. and Omori, M., Chem. Lett. 931 (1975).Google Scholar
3. Wynne, K.J. and Rice, R.W., Ann, Rev. Mater. Sci. 14, 297 (1984).Google Scholar
4. Tawada, Y., Kondo, M., Okamoto, H. and Hamakawa, Y., Solar Energy Mater. 6, 299 (1982).Google Scholar
5. Soraru, G.D., Babonneau, F. and Mackenzie, J.D., J. Non-Cryst. Solids 106, 256 (1988).Google Scholar
6. Liedtke, S., Jahn, K., Finger, F. and Fuhs, W., J. Non-Cryst. Solids 77&78, 849 (1985).Google Scholar
7. Davis, E.A. and Mott, N.F., Phil. Mag. 22, 903 (1970).Google Scholar
8. Babonneau, F., Soraru, G.D. and Mackenzie, J.D., in press in J. Mat. Science.Google Scholar