Hostname: page-component-68945f75b7-tmfhh Total loading time: 0 Render date: 2024-08-06T09:15:47.796Z Has data issue: false hasContentIssue false

Effect of Oxygen Transport and Resistivity of the Environment on the Corrosion of Steel

Published online by Cambridge University Press:  28 February 2011

E. Escalante
Affiliation:
National Institute of Standards and Technology, Gaithersburg, MD 20899
T. Oka
Affiliation:
Nippon Steel Corporation, Tokyo, Japan
U. Bertocci
Affiliation:
National Institute of Standards and Technology, Gaithersburg, MD 20899
Get access

Abstract

This study is directed at investigating the rate of corrosion and its spatial distribution that develop under conditions where transport of oxygen and conductivity of the environment are controlled over a wide range, including low conductivity as expected in the Yucca Mountain environment. The results indicate that the corrosion rate of steel is directly related to the rate of oxygen transport over several orders of magnitude, and increasing conductivity by one order of magnitude increases corrosion rate by a factor of two or three. Of greater significance is the result that indicates that as conductivity of the environment decreases, and corrosion rate decreases, the degree of localized attack increases.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] DOE, “Environmental Assessment - Yucca Mountain Site, Nevada Research and Development Area, Nevada”, DOE/RW-0073, Volume 2, U.S. Dept of Energy, May 1986.CrossRefGoogle Scholar
[2] DOE, “Environmental Assessment - Yucca Mountain Site, Nevada Research and Development Area, Nevada”, DOE/RW-0073, Volume 1, U.S. Dept of Energy, May 1986.CrossRefGoogle Scholar
[3] McCright, R.D., Weiss, H., “Corrosion Behavior of Carbon Steels Under Tuff Repository Environmental Conditions”, UCRL-90875, October 1984.CrossRefGoogle Scholar
[4] Oversby, V.M., McCright, R.D., “Laboratory Experiments Designed to Provide Limits on the Radionuclide Source Term For the NNWSI Project, Proceedings of Workshop on the Source Term for Radionuclide Migration From HLW or Spent Nuclear Fuel”, UCRL-91257, November 1984.Google Scholar
[5] Westerman, R. E., Pitman, S. G., Haberman, J. H., “Corrosion Testing of Type 304L Stainless Steel in Tuff Groundwater Environments”, UCRL 21005, SANL 616–007, NBS 1129, December 1987.CrossRefGoogle Scholar
[6] McCright, R. D., Weiss, H., Juhas, M., and Logan, R. W., “Selection of Candidate Canister Materials For High-Level Nuclear Waste Containment in a Tuff Repository”, UCRL-89988, April 1984.Google Scholar
[7] Jansen, G., “Expected Waste Package Performance for Nuclear Waste Repositories in Three Salt Formations, BMI/ONWI-655, August 1987.Google Scholar
[8] Handbook of Chemistry and Physics, 54th Edition, p. D-222.CRC Press, Cleveland, OH (1973).Google Scholar
[9] Adams, R. N., “Electrochemistry at Solid Electrodes”, p. 61. M. Dekker, N. Y. (1969).Google Scholar
[10] Escalante, E., Oka, T., and Bertocci, U., “Effect of Oxygen Transport and Resistivity of the Environment on the Corrosion of Steel - Final Report”, National Institute of Standards and Technology, NISTIR-90-4266, 1990.Google Scholar
[11] Mansfeld, F., “Advances in Corrosion Science and Technology”, Vol. 6, p. 163. Fontana, M. G., Staehle, R. W., eds. Plenum Press, New York (1976).Google Scholar
[12] Kasahara, K., and Kajiyama, F., Corrosion, 39, 475 (1983).CrossRefGoogle Scholar
[13] Romanoff, M., “Underground Corrosion”. NBS Circular 579 (1957).Google Scholar
[14] Gerhold, W.F., Escalante, E., Sanderson, B.T., “The Corrosion Behavior of Selected Stainless Steels in Soil Environments”, National Institute of Standards and Technology, NBSIR-81–2228, February 1981.Google Scholar
[15] ASTM-G 1–81. “Preparing, cleaning, and evaluating corrosion test specimens”. Vol. 03.02. ASTM, Philadelphia, PA.Google Scholar