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Elementary Degradation Aspects of a-Si Solar Cells

Published online by Cambridge University Press:  26 February 2011

W. Kusian
Affiliation:
Siemens Research Laboratories, Otto-Hahn-Ring 6, D-8000 Mfnchen 83
H. Pfleiderer
Affiliation:
Siemens Research Laboratories, Otto-Hahn-Ring 6, D-8000 Mfnchen 83
B. Bullemer
Affiliation:
Fed. Armed Forces University Munich, D-8014 Neubiberg
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Abstract

The degradation of amorphous silicon (a-Si) pin solar cells under prolonged illumination (Stabler-Wronski-Effect SWE) is investigated. We first measured the spectral response due to low-intensity illumination. The external collection efficiency Q is a function of the light wavelength λ and the applied voltage U. The functions Q(U) saturate for increasing reverse bias. Normalization to the saturation values defines the internal collection efficiency q. The functions q(U) for different λ cross through a nodal point with coordinates Uf, qf The voltage Uf represents the flat-band voltage of the uniform-field model. Our first SWE aspect consists of a substantial qf reduction caused by enhanced photocarrier recombination near the pi- and in-junctions. We additionally measured the photocharacteristics due to white illumination at a variable intensity ϕ The photocurrents vanish at the transition voltage Ut which is independent of ϕ for an undegraded cell. With advancing degradation, Ut decreases but Ut(ϕ) becomes an increasing function. The latter effect represents our second degradation aspect, supplementing the first one.

Type
Research Article
Copyright
Copyright © Materials Research Society 1988

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References

/1/ Kusian, W., Pfleiderer, H., Bullemer, B., Solar Cells 22 (1987) 239 Google Scholar
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