Hostname: page-component-848d4c4894-nmvwc Total loading time: 0 Render date: 2024-07-07T23:14:48.368Z Has data issue: false hasContentIssue false

Erbium Alloyed Aluminum Nitride Films for Piezoelectric Applications

Published online by Cambridge University Press:  01 February 2011

A. Kabulski
Affiliation:
kabulski@gmail.com, West Virginia University, Lane Department of Computer Science and Electrical Engineering, Morgantown, West Virginia, United States
V. R. Pagán
Affiliation:
vincent.pagan@gmail.com, West Virginia University, Lane Department of Computer Science and Electrical Engineering, Morgantown, West Virginia, United States
D Korakakis
Affiliation:
Dimitris.Korakakis@mail.wvu.edu, West Virginia University, Lane Department of Computer Science and Electrical Engineering, Morgantown, West Virginia, United States
Get access

Abstract

Aluminum nitride (AlN) films have been explored for sensor and actuator applications, but the resultant piezoelectric coefficient is still too low to make the films more competitive with more commonly used piezoelectric materials such as lead zirconate titanate (PZT). While AlN does have the disadvantage of a lower piezoelectric response, it does have the ability to maintain its piezoelectric properties above 400°C, something that is not possible with other piezoelectric materials. It is desirable to achieve a larger piezoelectric response for AlN in order to facilitate the integration of nitride based devices into existing technologies but conventional methods of improving the response by growing higher quality film only result in slight improvements in the piezoelectric response. A method of improving the d33 piezoelectric coefficient beyond any values found in literature may be possible by exploring methods of improving PZT films.

Rare earth doping has been reported to improve the piezoelectric properties of PZT resulting in significant increases in the piezoelectric coefficient. Research has been conducted using rare earth dopants to improve upon the optical properties of AlN, but the impact on piezoelectric effect has never been considered.

Thin, 250-1000 nm, AlN:Er films have been reactively sputtered using erbium (Er)/aluminum alloyed targets to explore any improvement in piezoelectric properties of the AlN:Er films as compared to AlN films. AlN films with 0.5 and 1.5% Er concentrations have been found to have piezoelectric coefficients that are larger than comparable ‘Er-free’ AlN films. AlN films with only 0.5% Er quantities were found to increase the d33 coefficient compared to a similar AlN film depending on the thickness of the film. This increase results in d33,f values greater than 7pm/V which is larger than most values found in literature. By increasing the Er content to 1.5%, values of d33,f were found to be as large as 15 pm/V. This enhanced piezoelectric response is still lower than that of PZT, but can be used to create superior actuator devices than that of typical AlN films.

Type
Research Article
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Goel, T.C., Pillai, P.K.C., Sharma, H.D., Tripathi, A.K., Tripathi, A., Pramila, C., and Govindan, A., International Symposium on Electrets (1994) 720724 Google Scholar
2. Garg, A. and Agrawal, D.C., Materials Science and Engineering B, 86 (2001) 134143 Google Scholar
3. Shannigrahi, S.R., Tay, F.E.H., Yao, K., and Choudhary, R.N.P, Journal of the European Ceramic Society, 24 (2004) 163170 Google Scholar
4. Gao, Y., Uchino, K., and Viehland, D., J. Appl. Phys., 92, 4 (2002)Google Scholar
5. Majumder, S.B., Dixit, A., Roy, B., Jia, W., and Katiyar, R.S., IEEE International Symposium on Applications of Ferroelectrics (2002) 111114 Google Scholar
6. Shannigrahi, S.R. and Tripathy, S., Ceramics International 33 (2007) 595600 Google Scholar
7. Fan, H. and Liu, L., J. Electroceram. (2007)Google Scholar
8. Martin, F., Muralt, P., Dubois, M.-A., and Pezous, A., J. Vac. Sci. Technol. A, v 22, n 2 (2004) 361365 Google Scholar