Hostname: page-component-848d4c4894-8kt4b Total loading time: 0 Render date: 2024-07-03T03:23:22.762Z Has data issue: false hasContentIssue false

External rf substrate biasing during a-Si:H film growth using the expanding thermal plasma technique

Published online by Cambridge University Press:  21 March 2011

A.H.M. Smets
Affiliation:
Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands
W.M.M. Kessels
Affiliation:
Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands
M.C.M. van de Sanden
Affiliation:
Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands
Get access

Abstract

The interchangeability of ion bombardment and deposition temperature during a-Si:H film growth at high deposition rates (10-42 Å/s) by means of the expanding thermal plasma has been studied. The ion bombardment is generated by applying an external rf bias voltage on the substrate. It is shown that the opto-electronic performance of the a-Si:H films improves considerably when a moderate rf substrate bias voltage (∼20-60 V) is applied, i.e. the photo response increases two orders of magnitude up to 106. Furthermore, it is also revealed that the additional energy supplied to the growth surface by the ion bombardment, makes a reduction of the deposition temperature by ∼100 °C possible, while preserving good material properties. On the basis of the results obtained, three effects caused by the rf substrate bias can be distinguished: creation of an additional growth flux, a reduction of the void incorporation, and an increase in the vacancy density.

Type
Research Article
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Smets, A.H.M., PhD Thesis, Eindhoven University of Technology, The Netherlands (2002), http://alexandria.tue.nl/extra2/200211441.pdf.Google Scholar
2. Smets, A.H.M., Kessels, W.M.M., and Sanden, M.C.M. van de, Mat. Res. Soc. Symp. Proc. Vol. 762, A10.3.1 (2003).Google Scholar
3. Smets, A.H.M., Kessels, W.M.M., and Sanden, M.C.M. van de, Appl. Phys. Lett. 82, 865 (2003).Google Scholar
4. Gordijn, A., Rath, J.K., and Schropp, R.E.I., Mat. Res. Soc. Symp. Proc. Vol. 762, A6.8.1 (2003).Google Scholar
5. Nelson, B.P., Iwaniczko, E., Mahan, A.H., Wang, Q., Xu, Y., Crandall, R.S., and Branz, H.M., Thin Solid Films 395, 292 (2001).Google Scholar
6. Martinu, L., Klemberg-Sapieha, J.E., Küttel, O.M., Raveh, A., and Wertheimer, M.R., J. Vac. Sci. Technol. A 12, 1360 (1994).Google Scholar
7. Ascche, F.J.H. van, Kessels, W.M.M., Vangheluwe, R., Mischke, W.S., Evers, M., and Sanden, M.C.M. van de, to be published in Thin Solid Films.Google Scholar
8. Hamers, E.A.G., Sark, W.G.J.H.M. van, Bezemer, J., Meiling, H., and Weg, W.F. van der, J. Non-Cryst. Sol. 226, 205 (1996).Google Scholar
9. Müller, K.H., Phys. Rev. B 35, 7906 (1987).Google Scholar
10. Smith, R.W. and Srolovitz, D.J., J. App. Phys. 79, 1448 (1996).Google Scholar
11. Kessels, W.M.M., Smets, A.H.M., Korevaar, B.A., Adriaenssens, G.J., Schram, D.C., and Sanden, M.C.M. van de, J. Appl. Phys. 89, 2404 (2001).Google Scholar
12. Smets, A.H.M., Kessels, W.M.M., and Sanden, M.C.M. van de, Appl. Phys. Lett. 82, 1547 (2003).Google Scholar
13. Kessels, W.M.M., Leeuwis, C.M., Sanden, M.C.M. van de, and Schram, D.C., J. Appl. Phys. 86, 4029 (1999)Google Scholar
14. Kessels, W.M.M., Leroux, A., Boogaarts, M.G.H., Hoefnagels, J.P.M., Sanden, M.C.M. van de, and Schram, D.C., J. Vac. Sci. Technol. A 19, 467 (2001).Google Scholar
15. Hoefnagels, J.P.M., Barrell, Y., Kessels, W.M.M., and M.C.M. van de Sanden, to be published.Google Scholar