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Glass Formation and Reddish Coloring Properties in Zinc Phosphotellurite Glass.

Published online by Cambridge University Press:  11 February 2011

Tomoya Konishi
Affiliation:
Advanced Materials Laboratory, National Institute for Materials Science, 1–1 Namiki, Tsukuba, Ibaraki 305–0047, JAPAN.
Takaharu Hondo
Affiliation:
Faculty of Industrial Science and Technology, Department of Materials Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278–8510, JAPAN.
Tetsuo Araki
Affiliation:
Faculty of Industrial Science and Technology, Department of Materials Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278–8510, JAPAN.
Keishi Nishio
Affiliation:
Faculty of Industrial Science and Technology, Department of Materials Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278–8510, JAPAN.
Toshio Tsuchiya
Affiliation:
Faculty of Industrial Science and Technology, Department of Materials Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278–8510, JAPAN.
Takehisa Matsumoto
Affiliation:
Advanced Materials Laboratory, National Institute for Materials Science, 1–1 Namiki, Tsukuba, Ibaraki 305–0047, JAPAN.
Shigeru Suehara
Affiliation:
Advanced Materials Laboratory, National Institute for Materials Science, 1–1 Namiki, Tsukuba, Ibaraki 305–0047, JAPAN.
Shin-ichi Todoroki
Affiliation:
Advanced Materials Laboratory, National Institute for Materials Science, 1–1 Namiki, Tsukuba, Ibaraki 305–0047, JAPAN.
Satoru Inoue
Affiliation:
Advanced Materials Laboratory, National Institute for Materials Science, 1–1 Namiki, Tsukuba, Ibaraki 305–0047, JAPAN.
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Abstract

Various compositions of P2O5-TeO2-ZnO glasses were prepared by using a combinatorial glass preparation system including a batch-preparing apparatus and a multi-sample casting machine, and the compositional dependence of glass forming tendency and thermal properties were intensively investigated. The samples exhibited a variety of colors, such as transparent, yellow, wine red and brown depending on its composition. Analyses with scanning electron microscopy and X-ray photoelectron spectroscopy revealed that the reddish coloration is responsible for colloidal suspension of nanometer sized elemental Te particles.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

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References

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