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Gravitationally Induced Convection During Directional Solidification of off-Eutectic Mn-Bi Alloys

Published online by Cambridge University Press:  15 February 2011

Ron G. Pirich*
Affiliation:
Metals Science Laboratory, Research Department, Grumman Aerospace Corporation, Bethpage, New York, USA
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Abstract

The effects of thermal and solute gradient, gravity induced convection during vertical directional solidification, on longitudinal macrosegregation of Bi and Mn rich off-eutectic starting compositions, has been studied as a function of composition, growth velocity and gravity vector orientation. Since the morphology of these alloys is characterized by an aligned, rodlike permanent magnet composite when grown cooperatively, the magnetic properties were used to measure composition segregation and the transition from dendritic to composite growth. Severe macrosegregation was observed in all cases studied and the degree of convection inferred by modeling the observed composition segregation using a stagnant film approach. Morphological stability was found to follow a constitutional supercooling-type law for both Bi and Mn rich compositions.

Type
Research Article
Copyright
Copyright © Materials Research Society 1982

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References

REFERENCES

1.Hertzberg, R.W., Fiber Composite Materials (ASM, Metals Park, Ohio, 1965) p. 83.Google Scholar
2.Sinclair, P.M., Ind. Res. 11, 59 (1969).Google Scholar
3.Pirich, R.G. et al. , Met. Trans. A 11A, 193 (1980).Google Scholar
4.Flemings, M.C., Surfaces and Interfaces II, Burke, J.J., Reed, N.L. and Weiss, V. eds. (Syracuse Univ. Press, Syracuse, New York, 1968) p. 348.Google Scholar
5.Verhoeven, J.D. and Homer, R.H., Met. Trans. 1, 3437 (1970).Google Scholar
6.Vandenbulcke, L., Herbin, R.J. and Vuillard, G., J. Crys. Growth 36, 53 (1976).Google Scholar
7.Verhoeven, J.D. et al. , Met, Trans. B 6B, 647 (1975).Google Scholar
8.Mollard, F.R. and Flemings, M.C., Trans. TMS-AIME 239, 1534 (1967).Google Scholar
9.Davis, K.G. and Fryzuk, P., Can. Metall. Quart. 10, 273 (1971).Google Scholar
10.Coriell, S.R. et al. , J. Crys. Growth 49, 13 (1980).Google Scholar
11.Sekerka, R.F. and Coriell, S.R., Fall TMS-AIME Mtg., Louisville, KY, 1981.Google Scholar
12.Pirich, R.G. and Larson, D.J., Fifth American Crys. Growth Conf., Paper IXB–6, Coronada, CA, 1981.Google Scholar
13.Pirich, R.G. et al. , AIAA Jnl. 19, 589 (1981).Google Scholar
14.Pirich, R.G., submitted to J. Crys. Growth.Google Scholar
15.Pirich, R.G. and Larson, D.J., Jnl. App. Phys. 50, 2425 (1979).Google Scholar
16.Pirich, R.G. et al. , IEEE Mag. Trans. 15, 1754 (1979).Google Scholar
17.Pirich, R.G., IEEE Mag. Trans. 16, 1065 (1980).Google Scholar
18.McCreight, L.R., Noone, M.J. and Locker, R.J., ESA publication 114, 1 (1974).Google Scholar
19.Smithells, C.J., Metals Reference Book (The Butterworth Group, London, 1976) p. 939.Google Scholar
20.Wilcox, W.R., Chem. Eng. Sci. 13, 113 (1961).Google Scholar