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Interfacial Electron Transfer in MoS2 Nanoclusters

Published online by Cambridge University Press:  10 February 2011

F. Parsapour  and
D.F. Kelley
F. Parsapour
Affiliation:
Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872
D.F. Kelley*
Affiliation:
Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872
*
*Author to whom correspondence should be addressed
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Abstract

The dynamics of photoinduced electron transfer between 3.0 nm diameter MoS2 nanoclusters and adsorbed electron acceptors have been studied using static and time resolved optical spectroscopy. Two types of electron acceptors are adsorbed on these nanoclusters: 2,2'-bipyridine and 4,4',5,5'-tetramethyl-2,2'-bipyridine. The results reported here focus on the interpretation of the strongly non-exponential electron transfer kinetics. Electron/hole recombination kinetics have previously been analyzed in terms of a simple distributed kinetics model, and this model is extended to include the case of interfacial electron transfer.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 571: Symposium W – Semiconductor Quantum Dots , 1999 , 197
Copyright
Copyright © Materials Research Society 2000

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References

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