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Investigation Of Luminescence And Absorption Spectra Of Bedt-Ttf And Its Ion Radical Salt

Published online by Cambridge University Press:  16 February 2011

M. E. Kozlov ,
Y Tanaka ,
M. Tokumotot  and
T. Tani
M. E. Kozlov
Affiliation:
Institute of Semiconductors, Ukraine Academy of Sciences, Kiev, Ukraine
Y Tanaka
Affiliation:
Electrotechnical Laboratory, 1–1–4 UMezono, Tsukuba, Ibaraki 305, Japan
M. Tokumotot
Affiliation:
Electrotechnical Laboratory, 1–1–4 UMezono, Tsukuba, Ibaraki 305, Japan
T. Tani
Affiliation:
Electrotechnical Laboratory, 1–1–4 UMezono, Tsukuba, Ibaraki 305, Japan
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Abstract

Luminescence with maximum near 1.96 eV of organic donor compound bis (ethylenedi-thio) tetrathiafulvalene (BEDT-TTF) was observed in crystals and frozen at low temperature solution. It was found that solid state effects sharply reveal themselves in excitation spectra of the substance and have almost no influence on the shape of the emission. Intensity of the emission is strong at liquid He temperature but rapidly decreases with heating of the sample as well as after modification of charged state of molecules forming the crystal and is very weak in case of Monovalent (BEDT-TTF) Br salt. Shape of the luminescence spectra correlates with the absorption of the investigated compounds. The data obtained can be interpreted assuming dimer-like arrangement of molecules in the crystal structure.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 328: Symposium Q – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1993 , 343
Copyright
Copyright © Materials Research Society 1994

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References

REFERENCES

1. Williams, J.M., Ferraro, J.R., Thorn, R.J., Carlson, K.D., Geiser, U., Wang, H.H., Kini, A.M. and Whangbo, M.-H., Organic Superconductors (Including Fullerens), (Prentice Hall, 1992), p. 52.Google Scholar
2. Kozlov, M.E., Pokhodnia, K.I. and Yurchenko, A.A., Spectrochim. Acta 43A, 323 (1987); 45A, 437 (1989).Google Scholar
3. Torrance, J.B., Scott, B.A., Welber, B., Kaufman, F.B. and Seiden, P.E., Phys. Rev. B 19, 730 (1979).Google Scholar
4. Sugano, T., Yakushi, K. and Kuroda, H., Bull. Chem. Soc. Japan 51, 1041 (1978).Google Scholar
5. Pope, M. and Swenberg, C.E., Electronic Processes in Organic Crystals, (Oxford University Press, New York, 1982), p.43.Google Scholar
6. Bozio, R., Zanon, I., Girlando, A. and Pecile, C., J. Chem. Phys. 71, 2282 (1989).Google Scholar
7. Kobayashi, H., Kobayashi, A., Sasaki, Y., Saito, G. and Inokuchi, H., Bull. Chem. Soc. Japan 59, 301 (1986).CrossRefGoogle Scholar
8. Mori, T., Kobayashi, A., Sasaki, Y., Kobayashi, H., Saito, G. and Inokuchi, H., Bui. Chem. Soc. Japan 57, 627 (1984).Google Scholar
9. Bender, K., Hennig, I., Schweitzer, D., Dietz, K., Endres, H., Keller, H.J., Mol. Cryst. Liq. Cryst. 108, 359 (1984).Google Scholar