Hostname: page-component-5c6d5d7d68-sv6ng Total loading time: 0 Render date: 2024-08-06T13:22:13.976Z Has data issue: false hasContentIssue false

Magnetic Properties of E21-base Co3AlC and the Correlation with the Ordering of Carbon Atoms and Vacancies

Published online by Cambridge University Press:  26 February 2011

Yoshisato Kimura
Affiliation:
Materials Science and Engineering, Tokyo Institute of Technology, 4259-G3–23 Nagatsuta, Midori-ku, Yokohama 226–8502, Japan.
Fu-Gao Wei
Affiliation:
National Institute for Materials Science, 1–2–1 Sengen, Tsukuba, Ibaraki 305–0047, Japan.
Hideyuki Ohtsuka
Affiliation:
National Institute for Materials Science, 1–2–1 Sengen, Tsukuba, Ibaraki 305–0047, Japan.
Yoshinao Mishima
Affiliation:
Materials Science and Engineering, Tokyo Institute of Technology, 4259-G3–23 Nagatsuta, Midori-ku, Yokohama 226–8502, Japan.
Get access

Abstract

Targeting to develop E21 Co3AlC based heat resistant alloys, phase stability of E21 Co3AlC and (Co, Ni)3AlC has been investigated together with the magnetic properties of E21’ Co3AlC0.5 which is formed by the extra ordering of carbon atoms accompanying anti-phase boundary (APB). The correlation of ferromagnetism with APB in E21’ Co3AlC0.5 was evaluated using single crystals by high-resolution transmission electron microscopy (HRTEM) and vibrating sample magnetometer. Anti-phase domain (APD) size affects the ferromagnetism: for instance, the saturation magnetization becomes larger as the APD size is smaller. Local atomic configuration at APB was clearly observed by HRTEM image.

Type
Research Article
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Huetter, L. J. and Stadelmaier, H. H., Acta Metal. 6, 367 (1958).Google Scholar
2. Nowotny, H., and Benesovsky, F., Phase Stability in Metals and Alloys, eds. Rudman, P. S. et al., McGraw Hill, New York, 319 (1967).Google Scholar
3. Stadelmaier, H. H., Developments in the Structural Chemistry of Alloy Phases, ed. Giessen, B. C., Plenum Press, New York, 141 (1969).Google Scholar
4. Hosoda, H., Takahashi, M., Suzuki, T. and Mishima, Y., High-Temperature Ordered Intermetallic Alloys V, MRS Symp Proc 288, 793 (1993).Google Scholar
5. Kimura, Y., Takahashi, M., Miura, S., Suzuki, T. and Mishima, Y., Intermetallics 3, 413 (1995).Google Scholar
6. Kimura, Y., Liu, C.T. and Mishima, Y., Intermetallics 9, 1069 (2001).Google Scholar
7. Wei, F.-G., Hwang, K.-Y. and Mishima, Y., Intermetallics 9, 671 (2001).Google Scholar
8. Kimura, Y., Iida, K. and Mishima, Y., Defect Properties and Related Phenomena in Intermetallic Alloys, MRS Symp Proc 753, 433 (2003).Google Scholar
9. Hosoda, H., Miyazaki, S. and Mishima, Y., J. Phase Equilibria 22, 394 (2001).Google Scholar
10. Kimura, Y., Sakai, K. and Mishima, Y., will be published in J. Phase Equilibria and Diffusion.Google Scholar
11. Villars, P., Prince, A. and Okamoto, H., eds., Handbook of Ternary Alloy Phase Diagrams, vol. 3, ASM Intnl., Materials Park, 3052 (1995).Google Scholar