Hostname: page-component-84b7d79bbc-7nlkj Total loading time: 0 Render date: 2024-07-30T21:20:33.863Z Has data issue: false hasContentIssue false
  • English
  • Français

Mixed Valent Rhodates

Published online by Cambridge University Press:  01 February 2011

Hiroshi Mizoguch ,
Arthur William Sleight  and
Mas Subramanian
Hiroshi Mizoguch
Affiliation:
mizoguch@science.oregonstate.edu, Oregon State University, Chemistry, Corvallis, Oregon, United States
Arthur William Sleight
Affiliation:
arthur.sleight@oregonstate.edu, Oregon State University, Chemistry, Corvallis, Oregon, United States
Mas Subramanian
Affiliation:
mas.subramanian@oregonstate.edu, Oregon State University, Chemistry, Corvallis, Oregon, United States
Get access

Abstract

Exploratory synthesis of mixed oxides of rhodium has produced many new rhodates containing both Rh3+ and Rh4+. The structures of all the compounds are based on networks formed from RhO6 octahedra sharing both corners and edges. All compounds exhibit good electrical conductivity, and some also show a high thermopower.

Keywords

Rhoxidethermoelectric
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1148: Symposium PP – Solid-State Chemistry of Inorganic Materials VII , 2008 , 1148-PP11-04
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Shimura, T., Itoh, M., Nakamura, T., J. Solid State Chem. 98, 198 (1992).Google Scholar
2. Stitzer, K.E., Smith, M.D, Darriet, J., zur Loye, H.-C., Chem. Commun. 1680 (2001).Google Scholar
3. Stitzer, K.E, Ahmed, E. A., Darriet, J., zur Loye, H.-C., J. Amer. Chem. Soc. 126, 856 (2004).Google Scholar
4. Siegrist, T., Larson, E.M., Chamberland, B.L., J.Alloys Comp. 210, 13 (1994).Google Scholar
5. Klimczuk, T., Lee, W.-L., Zandbergen, H.W., Cava, R.J., Mater.Res. Bull. 39, 1671(2004).Google Scholar
6. Plaisier, J.R., van Vliet, A.A.C., Ijdo, D.J.W., J.Alloys Comp. 314, 56 (2001).Google Scholar
7. Claridge, J.B., zur, H.-C. Loye, Chem Mater. 10, 2320 (1998).Google Scholar
8. Frampton, P.P.C., Battle, P.D., Ritter, C., Inorg.Chem. 44, 7138 (2005).Google Scholar
9. Mizoguchi, H., Marshall, W. J., Ramirez, A.P., Sleight, A.W., and Subramanian, M.A., J. Solid State Chem. 180, 3463 (2007).Google Scholar
10. Mizoguchi, H., Ramirez, A.P., Zakharov, L. N., Sleight, A.W., Subramanian, M.A., J. Solid State Chem. 181, 56 (2008).Google Scholar
11. Mizoguchi, H., Zakharov, L. N., Ramirez, A. P., Sleight, A. W., Subramanian, M. A., Inorg.Chem. (in press).Google Scholar
12. Mizoguchi, H., Zakharov, L. N., Ramirez, A. P., Marshall, W. J., Sleight, A. W., Subramanian, M. A. (submitted).Google Scholar
13. Post, J.E., Proc. Natl. Acad. Sci. USA 96, 3447 (1999).Google Scholar
14. Vicat, J., Fanchon, E., Strobel, P., Duc Tran, Q., Acta Crystallogra. B 42, 162 (1986).Google Scholar
15. Cheary, R.W., Acta Crystallogra. B 47, 325 (1991).Google Scholar
16. Stowasser, F., Renkenberger, C., Z.Krist. 221, 206 (2006).Google Scholar
17. Müller-Buschbaum, H., Muschick, W., Anorg, Z.. Allgem.Chem. 412, 209 (1975).Google Scholar