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Nanostructure Evolution During Processing of Thin-Film Gels: A High-Resolution Electron Microscopic Study. 2. The Thin-Film Gel Derived From Pb(Zr0.45Ti0.55)O2 (OR) 2

Published online by Cambridge University Press:  21 February 2011

C. Kang ,
S. K. Dey  and
L. Eyring
C. Kang
Affiliation:
Department of Chemistry and Center for Solid State Science, Arizona State University, Tempe, AZ 85287
S. K. Dey
Affiliation:
Department of Chemical, Bio, and Materials Engineering and Center for Solid State Electronics Research, Arizona State University, Tempe, AZ 85287
L. Eyring
Affiliation:
Department of Chemistry and Center for Solid State Science, Arizona State University, Tempe, AZ 85287
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Abstract

High-resolution electron microscopic examination of alkoxide thin-film gels has been employed to study the drying and aging of thin-film Pb(Zr0.45Ti0.55)O2 (OR) 2 as it evolves from the gel to the ferroelectric perovskite product. The initially amorphous film is observed to aggregate to form ordered islands with inter-metal distances close to that of the final structure embedded in a highly disordered matrix. When these aggregates are at the surface they grow and decompose more rapidly to the perovskite product. The progress to a polycrystalline final state is followed and recorded in real time and in time-lapse at high resolution.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 183: Symposium E – High Resolution Electron Microscopy of Defects in Materials , 1990 , 291
Copyright
Copyright © Materials Research Society 1990

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References

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