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Novel Approach for Biofouling-Release Materials with Interpenetrating Polymer Networks

Published online by Cambridge University Press:  26 February 2011

Kenji Mori ,
Masanobu Naito ,
Takashi Nakai ,
Michiya Fujiki  and
Takuma Kawabe
Kenji Mori
Affiliation:
m-kenji@ms.naist.jp, Nara Institute of Science and Technology, 8916-5, Takayama, Ikoma, Nara, 630-0101, Japan, +81-743-72-6043, +81-743-72-6049
Masanobu Naito
Affiliation:
mnaito@ms.naist.jp
Takashi Nakai
Affiliation:
nakai1979@mac.com
Michiya Fujiki
Affiliation:
fujikim@ms.naist.jp
Takuma Kawabe
Affiliation:
k-takuma@ms.naist.jp
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Abstract

Environmentally friendly organic-inorganic hybrid materials with repellent activity against marine fouling organisms, such as blue mussel, have been developed using interpenetrating polymer networks (IPNs), composed of a 3-dimensional siloxane matrix of tetraethoxysilane (TEOS) and poly(vinylacetate) (PVAc). Facile bioassay using blue mussels allowed screening the adequate proportions of those components. The repellent activity of IPN with PVAc/silica reached approximately 90% at a specific fraction, relative to that of tributyl tin oxide (TBTO). On the other hand, poly(methylmethacrylate)(PMMA) /silica composite did not show marked repellent activity against blue mussel, even though chemical structure of MMA is similar to that of vinylacetate.

Keywords

environmentally protectiveblendcomposite
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 897: Symposium J – Biomemetic Polymers and Gels , 2005 , 0897-J03-02
Copyright
Copyright © Materials Research Society 2006

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References

1. Omae, I., Chem. Rev., 103, 3431 (2003).Google Scholar
2. Mera, A. E. and Wynne, K. J., U. S. Patent 62665515 (2001).Google Scholar
3. Ina, K., Takasawa, R., Yagi, A., Yamashita, N., Eto, H., and Sakata, K., Agric. Biol. Chem., 53, 3319 (1989).Google Scholar
4. Yu, M., Hwang, J., and Deming, T. J., J. Am. Chem. Soc., 121, 5825 (1999).Google Scholar
5. (a) Coyne, K. J., Qin, X. –X.., and Waite, J. H., Science, 277, 1830 (1997), (b) J. H. Waite and M. L. Tanzer, Science, 212, 1038 (1981).Google Scholar
6. Bourlinos, A. B., Karakassides, M. A., and Petridis, D., J. Phys. Chem. B, 104, 4375 (2000).Google Scholar
7. Vallet-Regi, M., Salinas, A. J., Ramirez-Castellanos, J., and Gonzalez-Calbet, J. M., Chem. Mater. ASAP article (2005).Google Scholar