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The Polyanilines: a Novel Class of Conducting Polymers

Published online by Cambridge University Press:  25 February 2011

Alan G. Macdiarmid  and
Arthur J. Epstein
Alan G. Macdiarmid
Affiliation:
Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104–6323
Arthur J. Epstein
Affiliation:
Department of Physics and Department of Chemistry, The Ohio State University, Columbus, Ohio 43210–1106
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Abstract

The synthesis of polyaniline in its fully oxidized, fully reduced and selected average intermediate oxidation states is described together with the synthesis of a self-protonic acid doped polyaniline. The processing of polyaniline films and fibers by thermal stretching to give conductivities up to ∼100 S/cm is reported. Both doped and undoped polyaniline fibers have tensile strengths approaching those of commercial polymers.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 173: Symposium Q – Advanced Organic Solid State Materials , 1989 , 283
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

1. Chiang, J-C. and MacDiarmid, A.G., Synth. Met. 13, 193 (1986).CrossRefGoogle Scholar
2. MacDiarmid, A.G., Chiang, J-C., Richter, A.F., Somasiri, N.L.D. and Epstein, A.J., Conducting Polymers, edited by Alcacér, L. (Reidel Publications, Dordrecht, 1987).Google Scholar
3. Chiang, J-C., PhD. dissertation, University of Pennsylvania, (1987).Google Scholar
4. Kaplan, S., Conwell, E.M., Richter, A.F. and MacDiarmid, A.G., Synth. Met. 29, E235 (1989).Google Scholar
5. Richter, A.F., Ray, A., Ramanathan, K.V., Manohar, S.K., Furst, G.T., Opella, S.J., MacDiarmid, A.G. and Epstein, A.J., Synth. Met. 29, E243 (1989).CrossRefGoogle Scholar
6. Ray, A., Ph.D. dissertation, University of Pennsylvania, (1989).Google Scholar
7. MacDiarmid, A.G., Chiang, J-C., Richter, A.F. and Epstein, A.J., Synth. Met. 18, 285 (1987).Google Scholar
8. McManus, P.M., Yang, S.C. and Cushman, R.J., J. Chem. Soc. Chem. Commun. 1556 (1985).Google Scholar
9. Wnek, G.E., Synth. Met. 15, 213 (1986).Google Scholar
10. Epstein, A.J., Ginder, J.M., Zuo, F., Bigelow, R.W., Woo, H.S., Tanner, D.B., Richter, A.F., Huang, W-S. and MacDiarmid, A.G., Synth. Met. 18, 303 (1987);Google Scholar
Ginder, J.M., Richter, A.F., MacDiarmid, A.G. and Epstein, A.J., Solid State Commun. 63, 97 (1987).CrossRefGoogle Scholar
11. Gregory, R.V.. Kimbrell, W.C. and Kuhn, H.H., Synth. Met. 28, C-823 (1989).Google Scholar
12. Manohar, S.K., MacDiarmid, A.G. and Epstein, A.J., Bull. Am. Phys. Soc. 34, 582 (1989);Google Scholar
Manohar, S.K., MacDiarmid, A.G. and Epstein, A.J., 1989, unpublished observations.Google Scholar
13. Yue, J., Epstein, A.J. and MacDiarmid, A.G., to be published (1989).Google Scholar
14. Green, A.G. and Woodhead, A.E., J. Chem. Soc. Trans. 97, 2388 (1910).Google Scholar
15. Green, A.G. and Woodhead, A.E., J. Chem. Soc. Trans. 101, 1117 (1912).CrossRefGoogle Scholar
16. Masters, J., Manohar, S.K., Ray, A., MacDiarmid, A.G. and Epstein, A.J., unpublished results; A. Ray Ph.D. dissertation, University of Pennsylvania, (1989).Google Scholar
17. Sun, Y., MacDiarmid, A.G. and Epstein, A.J., unpublished observations, (1989).Google Scholar
18. Huang, W-S., MacDiarmid, A.G. and Epstein, AJ., J. Chem.Soc., Chem. Commun., 1784.(1987) .Google Scholar
19. Huang, W-S., Humphrey, B.D. and MacDiarmid, A.G., J. Chem. Soc. Faraday Trans. 1 82, 2385 (1986).Google Scholar
20. Sun, Y., MacDiarmid, A.G. and Epstein, A.J., unpublished observations, (1989).Google Scholar
21. MacDiarmid, A.G., Asturias, G.E., Kershner, D.L., Manohar, S.K., Ray, A., Scherr, E.M., Sun, Y., Tang, X. and Epstein, A.J., Polymer Preprints 30–1. 147 (1989).Google Scholar
22. Tang, X., Sun, Y. and Wei, Y., Makromol. Chem., Rapid Commun., 829, 9 (1988).Google Scholar
23. Masters, J.G., Sun, Y., MacDiarmid, A.G. and Epstein, A.J., unpublished observations (1989).Google Scholar
24. Shacklette, L.W., Wolfe, J.F., Gould, S. and Baughman, R.H., J. Chem. Phys. 88, 3955 (1988).Google Scholar
25. Angelopoulos, M., Asturias, G.E., Ermer, S.P., Ray, A., Scherr, E.M., MacDiarmid, A.G., Akhtar, M., Kiss, Z. and Epstein, A.J., Mol. Cryst. Liq. Cryst. 160, 151 (1988).Google Scholar
26. Andreatta, A., Cao, Y., Chiang, J-C., Heeger, A J. and Smith, P., Synth. Met. 26, 383 (1988).CrossRefGoogle Scholar
27. Angelopoulos, M., Ray, A., MacDiarmid, A.G. and Epstein, A.J., Synth. Met. 21.21 (1987).Google Scholar
28. Tang, X., Scherr, E., MacDiarmid, A.G. and Epstein, A.J., Bull. Am. Phys. Soc. 34, 583 (1989).Google Scholar
29. Tang, X., MacDiarmid, A.G., Epstein, A.J. and Wei, Y., unpublished observations, (1989).Google Scholar
30. Jozefowicz, M.E., Laversanne, R., Javadi, H.H.S., Epstein, A.J., Pouget, J.P., Tang, X. and MacDiarmid, A.G., Phys. Rev. B, Rapid Commun. 39, 12958 (1989).Google Scholar
31. Epstein, A.J. and MacDiarmid, A.G., Electronic Properties of Conjugated Polymer, editors Kuzmany, H., Mehring, M. and Roth, S., Springer-Verlag, Berlin (1989) in press.Google Scholar
32. Cromack, K.R., Jozefowicz, M.E., Ginder, J.M., McCall, R.P., Epstein, A.J., Scherr, E.M. and MacDiarmid, A.G., Bull. Am. Phys. Soc. 34, 583 (1989).Google Scholar
33. Scherr, E.M., MacDiarmid, A.G. and Epstein, A. J., unpublished observations, (1989).Google Scholar
34. Theophilou, N., MacDiarmid, A.G., Djurado, D., Fischer, J.E. and Epstein, A J., Electronic Properties of Conjugated Polymers, edited by Kuzmany, H., Mehring, M. and Roth, S., Springer-Verlag, Berlin, (1989) in pressGoogle Scholar