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Preparation of 110k Superconductor in Bi-Sr-Ca-Cu-O System

Published online by Cambridge University Press:  28 February 2011

Chen Zuyao
Affiliation:
(Laboratory of Crystal Chemistry and Functional Materials, Department of Applied Chemistry, Univ. of Science and Technology of China, Hefei, Anhui 230026, P.R.China) Xia Jiansheng, Wang Shunxi (Department of Physics, Univ. of Science and Technology of China)
Lin Rong
Affiliation:
(Laboratory of Crystal Chemistry and Functional Materials, Department of Applied Chemistry, Univ. of Science and Technology of China, Hefei, Anhui 230026, P.R.China) Xia Jiansheng, Wang Shunxi (Department of Physics, Univ. of Science and Technology of China)
Chen Xianhui
Affiliation:
(Laboratory of Crystal Chemistry and Functional Materials, Department of Applied Chemistry, Univ. of Science and Technology of China, Hefei, Anhui 230026, P.R.China) Xia Jiansheng, Wang Shunxi (Department of Physics, Univ. of Science and Technology of China)
Qian Yitai
Affiliation:
(Laboratory of Crystal Chemistry and Functional Materials, Department of Applied Chemistry, Univ. of Science and Technology of China, Hefei, Anhui 230026, P.R.China) Xia Jiansheng, Wang Shunxi (Department of Physics, Univ. of Science and Technology of China)
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Abstract

To explore high Tc in Bi-Sr-Ca-Cu-O system, many different nominal compositions have been prepared by using the traditional solid state reactions and using the method of crystallizion from glass samples. The better results are as follows: single high-Tc phase and essentially single high-Tc phase have been obtained from Bi1.8Pb0.35Sr2Ca2Cu3O and Bi2Sr2Ca6Cu7O respectively, by solid reaction. Basically single hign-T phase material with nominal composition Bi2Sr2Ca3Cu4Oy has been produced by the method of crystallizion from glass samples. The relationship between the starting composition heat treatment, preparation methods and high Tce is briefly discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1990

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References

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