Hostname: page-component-848d4c4894-4rdrl Total loading time: 0 Render date: 2024-07-05T06:22:21.006Z Has data issue: false hasContentIssue false
  • English
  • Français

Pressure and Temperature Effects on the Raman Spectra of Aqueous Micellar Solutions of Sodium Oleate

Published online by Cambridge University Press:  21 February 2011

P.T.T. Wong  and
H.H. Mantsch
P.T.T. Wong
Affiliation:
Division of Chemistry, National Research Council of Canada Ottawa, Ontario, CanadaK1A OR6
H.H. Mantsch
Affiliation:
Division of Chemistry, National Research Council of Canada Ottawa, Ontario, CanadaK1A OR6
Get access

Extract

Sodium oleate is practically insoluble in water at room temperature. Yet, when heated above the critical micellization temperature (cmt), its solubility increases rapidly and an isotropic optically clear micellar solution is formed. Upon cooling below the critical coagelization temperature (cct), the micellar phase transforms to an opaque curd, the coagel phase. The structural changes and the nature of this phase transition are, however, not well characterized.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 22: Symposium NY – High Pressure in Science and Technology , 1983 , 129
Copyright
Copyright © Materials Research Society 1984

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Wong, P.T.T. and Mantsch, H.H., Can. J. Chem. 60, 2137 (1982).Google Scholar
2. Wong, P.T.T., Murphy, W.F., and Mantsch, H.H., J. Chem. Phys. 76, 5230 (1982).Google Scholar
3. Long, T.V. and Plane, R.A., J. Chem. Phys. 43, 457 (1965).Google Scholar
4. Lippincott, E.R. and Nagerajan, G., Bull. Soc. Chim. Belg. 74, 551 (1965).Google Scholar
5. Fontal, B. and Spiro, T.G., Spectrochim. Acta. Part A, 33, 507 (1977).Google Scholar
6. Snyder, R.G., Hsu, S.L., and Krimm, S., Spectrochim. Acta. Part A, 34, 395 (1978).Google Scholar
7. Gaber, B.P. and Peticolas, W.L., Biochim. Biophys. Acta. 465, 260 (1977).CrossRefGoogle Scholar