Hostname: page-component-848d4c4894-89wxm Total loading time: 0 Render date: 2024-07-06T08:25:34.960Z Has data issue: false hasContentIssue false

Processing of Organic/Inorganic Composites by Stereolithography

Published online by Cambridge University Press:  10 February 2011

J. H. Lee
Affiliation:
Department of Chemical Engineering and Princeton Materials Institute, Princeton University, Princeton, NJ 08544
R. K. Prud'homme
Affiliation:
Department of Chemical Engineering and Princeton Materials Institute, Princeton University, Princeton, NJ 08544
I. A. Aksay
Affiliation:
Department of Chemical Engineering and Princeton Materials Institute, Princeton University, Princeton, NJ 08544
Get access

Abstract

Ceramic StereoLithography (CSL) is used to fabricate complex shaped ceramic powder compacts by laser photocuring a concentrated ceramic dispersion in photocuring solutions layer-by-layer. The main processing parameters in CSL such as layer thickness, resolution, hatch spacing, and overcure depend on knowledge of the light propagation in a concentrated dispersion. In studies dealing with the processing of ceramic-filled organics, we investigated the depth of curing for model resin systems as a function of photoinitiator concentration. An optimal photoinitiator concentration that maximized the gel cure depth was observed The study showed that photoinitiator plays a significant role in controlling the quality and performance of the formed gel network, with special regard to thickness of cured layers. This has potential application to fields as diverse as industrially cured coatings and dental fillings, and more generally, 3-dimensional fabrication techniques.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Jacobs, P.F., Rapid Prototyping & Manufacturing, (Soc. of Manufacturing Engineers, Dearborn, MI 1992).Google Scholar
2 Jacobs, P.F., Stereolithography and other RP&M Technologies (Soc. of Manufacturing Engineers, Dearborn, MI 1996).Google Scholar
3 Hench, L.L., “Bioceramics,” J. Am. Ceram. Soc. 81 [7] 1705–28 (1998).Google Scholar
4 Bonfield, W., Grynpas, M.D., Tully, A.E. et al. , “Hydroxyapatite Reinforced Polyethylene - a Mechanically Compatible Implant Material For Bone-Replacement,” Biomaterials 2 [3] 185–86 (1981).Google Scholar
5 Garg, R., “Stereolithography of Ceramics,” Ph.D. dissertation (Princeton University, Princeton, NJ, 1999).Google Scholar
6 Garg, R., Prud'homme, R.K., Aksay, I.A., Liu, F., and Alfano, R., “Optical Transmission in Highly-Concentrated Dispersions,” J. Opt. Soc. Am. 15 [4] 932–35 (1998).Google Scholar
7 Garg, R., Prud'homme, R.K., Aksay, I.A., Liu, F., and Alfano, R., “Absorption Length for Photon Propagation in Highly Dense Colloidal Dispersions,” J. Mater. Res. 13 [12] 3463–67 (1998).Google Scholar
8 Brady, G.A. and Halloran, J.W., “Differential Photo-calorimetry of Photopolymerizable Ceramic Suspensions,” J. Mater. Sci. 33 [18] 4551–60 (1998).Google Scholar
9 Rueggeberg, F.A., Lockwood, P.E., and Ergle, J.W., “Effect of Post-cure Heating and Photoinitiator Level on a Model Resin System,” J. Dental Res. 76 472–72 (1997).Google Scholar
10 Rueggeberg, F.A., Ergle, J.W., and Lockwood, P.E., “Effect of Photoinitiator Level on Properties of a Light-cured and Post-cure Heated Model Resin System,” Dental Materials 13 [5-6] 360–64 (1997).Google Scholar
11 Lee, J.H., Prud'homme, R.K., and Aksay, I.A., “Cure Depths in Photopolymerization: Theory and Experiments,” J. Mater. Res. submitted (2000).Google Scholar