Hostname: page-component-7bb8b95d7b-pwrkn Total loading time: 0 Render date: 2024-09-11T16:20:36.405Z Has data issue: false hasContentIssue false

Rheological and Optical Properties of Shearing Colloidal Suspensions by Polarized Light Spectroscopy

Published online by Cambridge University Press:  25 February 2011

Norman J. Wagner*
Affiliation:
Department of Chemical Engineering, University of Delaware Newark, DE 19716
Get access

Abstract

The two-particle correlation function serves as an important connection between suspension microstructure, scattering experiments, and macroscopic properties. Formal relationships between the experimentally accessible structure factor for suspensions undergoing simple shear, bulk stresses, and flow dichroism and birefringence are demonstrated. Measurements of flow dichroism using variable wavelength incident radiation provide a method to map out the nonequilibrium microstructure.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Ackerson, B.J., Kruif, C.G. de, Wagner, N.J., and Russel, W.B.. J. Chem. Phys., 60:3250, 1989.CrossRefGoogle Scholar
[2] Ackerson, B.J., Werff, J. van der, and Kruif, C.G. de. Phys. Rev. A., 37:4819, 1988.Google Scholar
[3] Wagner, N.J., Fuller, G.G, and Russel, W.B.. J. Chem. Phys., 89:1580, 1988.Google Scholar
[4] Wagner, N.J. and Russel, W.B.. Physics of Fluids, 2:491, 1990.CrossRefGoogle Scholar
[5] Ashdown, S., Markovic, I., Ottewill, R.H., Lindner, P., Oberthur, R.C., and Rennie, A.R.. Langmuir, 6:303, 1990.Google Scholar
[6] Felderhof, B.U. and Jones, R.B.. Physicea A, 146:417, 1987.Google Scholar
[7] Hess, W. and Klein, R.. Adv. Phys., 33:173, 1983.Google Scholar
[8] Wagner, N.J. and Russel, W.B.. Physica, 155 A:475, 1989.Google Scholar
[9] Batchelor, G.K.. J. Fluid Mech., 74:1, 1976.Google Scholar
[10] Russel, W.B. and Gast, A.P.. J. Chem. Phys., 89:1580, 1988.Google Scholar
[11] Dhont, J.K.G.. Journal of Fluid Mechanics, 204:421, 1989.Google Scholar
[12] Ronis, D.. Phys. Rev. A., 34:1472, 1986.Google Scholar
[13] Wagner, N.J. and Klein, R.. Coll. and Poly. Sci., 269:295, 1991.Google Scholar
[14] Wagner, N.J. and Ackerson, B.J.. Accepted by. Journal of Chemical Physics, 1992.Google Scholar
[15] Batchelor, G.K.. J. Fluid. Mech., 83:97, 1977.Google Scholar
[16] Felderhof, B.U.. Physica A, 147:203;533, 1987.CrossRefGoogle Scholar
[17] Frattini, P.L. and Fuller, G.G.. J. Fluid mech., 168:119, 1986.Google Scholar
[18] Johnson, S.J., Frattini, P.L., and Fuller, G.G.. J. Coll. Int. Sci., 104:440, 1985.CrossRefGoogle Scholar
[19] Onuki, A. and Doi, M.. J. Chem. Phys., 85:1190, 1986.Google Scholar
[20] Adriani, P.M. and Gast, A.P.. J. Chem. Phys., 91:6282, 1989.Google Scholar
[21] Wagner, N.J.. J. Chem. Phys., 94:6931, 1991.CrossRefGoogle Scholar
[22] Wagner, N.J.. Statistical Mechanics of Concentrated Dispersions. PhD thesis, Princeton University, 1989.Google Scholar
[23] deKruif, C.G., lersel, E.M.F van, Vrij, A., and Russel, W.B.. J. Chem. Phys., 83:4717, 1985.CrossRefGoogle Scholar