Hostname: page-component-7479d7b7d-8zxtt Total loading time: 0 Render date: 2024-07-10T08:30:28.376Z Has data issue: false hasContentIssue false

Si Whisker Growth by Hydrogen Radical using Hot Filament CVD Reactor

Published online by Cambridge University Press:  01 February 2011

Hiroshi Nagayoshi
Affiliation:
nagayosi@r2.dion.ne.jp, Tokyo National College of Technology, Electronic Engineering, 1220-2, Kunugida-machi, Hachioji, N/A, Japan, +81-42-723-9608
Suzuka Nishimura
Affiliation:
toraka0623@yahoo.co.jp, Shonan Institute of Technology, 1-1-25, Tsujido, Fujisawa, Kanagawa, Japan
Kazutaka Terashima
Affiliation:
terashima@mate.shonan-it.ac.jp, Shonan Institute of Technology, 1-1-25, Tsujido, Fujisawa, Kanagawa, Japan
Nobuo Matsumoto
Affiliation:
matumoto@elec.shonan-it.ac.jp, Shonan Institute of Technology, 1-1-25, Tsujido, Fujisawa, Kanagawa, Japan
Alexander G. Ulyashin
Affiliation:
alexander.ulyashin@ife.no, Institute for Energy Technology, P.O.Box 40, Kjeller, NO-2027, Norway
Get access

Abstract

This paper describes the growth mechanism of silicon whisker on a silicon substrate using hot filament CVD reactor. Only hydrogen is used as source gas. The particle layer could be obtained at high filament current condition under hydrogen ambient. XPS analysis result suggests that the particle is composed of tungsten silicide. The deposition condition of the particle layer is much depended on the substrate size, surface condition and the distance between the substrate and the filament. The experimental results suggest that the silicon hydride, which generated at the silicon surface by hydrogen radical etching, react with the tungsten filament material around the filament, depositing on the silicon substrate. The silicon surface is etched by hydrogen radical and its resultant surface morphology is much depended on the particle deposition pattern. Many silicon whiskers, which diameter is varied from 10 to 50 nm, are observed on the textured silicon surface when the residence time of the source gas in the reactor is long. Each whisker has a silicon particle on their tip. The silicon hydride generated by the hydrogen radical etching is much absorbed to the silicide particle when the source gas residence time is long, enabling the silicon whisker growth from the particle. The results suggest that nm size whisker structure is much stable compare to the bulk silicon against etching reaction.

Type
Research Article
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Huang, Y., Duan, X., Hu, J., and M, C.. Lieber, Science 291, 630 (2001)Google Scholar
2. Cui, Y., Lauhon, L. J., Gudiksen, M. S., Wang, K. L., and Lieber, C. M., Appl. Phys. Lett 78, 2214 (2001).Google Scholar
3. Liu, J. L., Cai, S. J., Jin, G. L., Thomas, S. G., and Wang, K. L., J. Cryst. Growth 200, 106 (1999).Google Scholar
4. Morales, A. M. and Lieber, C. M., Science 279, 208 (1998).Google Scholar
5. Zhang, Y. F., Tang, Y. H., Wang, N., Yu, D. P., Lee, C. S., Bello, I., and Lee, S. T., Appl. Phys. Lett. 72, 1835 (1998).Google Scholar
6. Barsotti, R. J. Jr., Fischer, J. E., Lee, C. H., Mahmood, J., Adu, C. K. W., Eklund, P. C., Appl. Phys. Lett. 81, 15(2002) 2866 Google Scholar
7. Wagner, R. S., Ellis, W. C., Jackson, K., and Arnold, S. M., J. Appl. Phys. 35, 2993 (1964).Google Scholar
8. Giargizov, E. I., J. Cryst. Growth 31, 20 (1975).Google Scholar
9. Chang, R. P., Chang, C. C. and Darack, S., J. Vac. Sci. Technol., 20(1), 45 (1982).Google Scholar
10. Nagayoshi, H., Nishimura, S., Treashima, K., Konno, K., Jpn. J. Appl. Phys., 44, 7839 (2005).Google Scholar