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Sol-gel Nanohybrid Materials Incorporating Functional Thiacalixarenes for Non-Linear Optical Applications

Published online by Cambridge University Press:  15 February 2011

C. Desroches ,
S. Parola ,
D. Cornu ,
P. Miele ,
P. L. Baldeck  and
C. Lopes
C. Desroches
Affiliation:
Laboratoire des Multimatériaux et Interfaces, UMR 5615 CNRS, Université Claude Bernard-Lyon 1, 69622 Villeurbanne, France. E-mail:Stephane.Parola@univ-lyon1.fr
S. Parola
Affiliation:
Laboratoire des Multimatériaux et Interfaces, UMR 5615 CNRS, Université Claude Bernard-Lyon 1, 69622 Villeurbanne, France. E-mail:Stephane.Parola@univ-lyon1.fr
D. Cornu
Affiliation:
Laboratoire des Multimatériaux et Interfaces, UMR 5615 CNRS, Université Claude Bernard-Lyon 1, 69622 Villeurbanne, France. E-mail:Stephane.Parola@univ-lyon1.fr
P. Miele
Affiliation:
Laboratoire des Multimatériaux et Interfaces, UMR 5615 CNRS, Université Claude Bernard-Lyon 1, 69622 Villeurbanne, France. E-mail:Stephane.Parola@univ-lyon1.fr
P. L. Baldeck
Affiliation:
Laboratoire de Spectrométrie Physique, UMR 5588 CNRS, Université Joseph Fourier, Saint Martin d'Hères, France
C. Lopes
Affiliation:
Swedish Defence Research Agency, Division of Sensor Technology, 581 11, Linköping, Sweden
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Abstract

Macrocyclic thiacalixarenes have interesting non-linear optical properties. Thiacalixarenes bearing phenylazo, imino, ethynylic groups or platinum derived acetylides on the upper rims were designed, prepared and fully characterised. They showed interesting properties for optical limiting. Moreover these macrocycles are highly soluble in organic solvents and can easily be embedded in inorganic matrix using the sol-gel routes.

Thiacalixarene based class I and II solid-state materials were prepared and their optical limiting behaviour was investigated.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 771: Symposium L – Organic and Polymeric Materials and Devices , 2003 , L7.16
Copyright
Copyright © Materials Research Society 2003

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