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Sol-Gel Route To Oxygen Ion Conductors in Thin Film Form

Published online by Cambridge University Press:  15 February 2011

J. W. Pell
Affiliation:
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139
K. M. Delak
Affiliation:
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139
H.-C. zur Loye
Affiliation:
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139
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Abstract

The oxygen-ion conducting Aurivillius phases Bi2Cu0.1V0.9O5.35 and Bi2Nb0.3V0.7O5.5 were synthesized as bulk powders by the sol-gel method, and gave single-phase powder X-ray diffraction patterns at calcination temperatures as low as 450 °C. Crack-free films of both materials were spin-coated onto quartz, platinum, and silver substrates and heat-treated in a twostep firing process. The effects of different process parameters were investigated.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

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