Hostname: page-component-77c89778f8-cnmwb Total loading time: 0 Render date: 2024-07-23T03:25:39.951Z Has data issue: false hasContentIssue false
  • English
  • Français

Solvothermal Synthesis and Characterization of Zn(NH3)CO3 Single Crystal

Published online by Cambridge University Press:  15 March 2011

Fushan Wen ,
Jiesheng Chen ,
Jin Hyeok Kim ,
Taeun Kim  and
Wenlian Li
Fushan Wen
Affiliation:
Photonic and Electronic Thin Film Laboratory, Department of Materials Science and Engineering, Chonnam National University, 300 Yongbong-Dong Puk-Gu Kwangju South Korea, 500-757 State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, College of Chemistry, Jilin University, 119 Jiefang Road, Changchun, 130023, P. R. China Key Laboratory of the Excited States Process, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033, People's Republic of China
Jiesheng Chen
Affiliation:
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, College of Chemistry, Jilin University, 119 Jiefang Road, Changchun, 130023, P. R. China
Jin Hyeok Kim
Affiliation:
Photonic and Electronic Thin Film Laboratory, Department of Materials Science and Engineering, Chonnam National University, 300 Yongbong-Dong Puk-Gu Kwangju South Korea, 500-757
Taeun Kim
Affiliation:
Photonic and Electronic Thin Film Laboratory, Department of Materials Science and Engineering, Chonnam National University, 300 Yongbong-Dong Puk-Gu Kwangju South Korea, 500-757
Wenlian Li
Affiliation:
Key Laboratory of the Excited States Process, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033, People's Republic of China
Get access

Abstract

A new 3-dimensional zinc carbonate Zn(NH3)CO3 has been synthesized from a glycol system with urea and zinc acetate as raw materials. The crystal structure and photoluminescent properties have been investigated using X-ray diffraction, smart CCD and FL. The compound had an orthorhombic system with space group of Pna21 with M = 142.41, a = 9.1449(18) Å, b = 7.5963(15) Å, c = 5.4982(11) Å, V = 381.95(13) Å3, Z = 4, R = 0.0285 and RW = 0.0745. The NH3 and CO32- were connected through the Zn-N bond and Zn-O bond in the symmetric unit. Photoluminescent property was observed in the compound at room temperature and the exited and emission peaks were located at about 350 nm and 426 nm, respectively.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 817: Symposium L – New Materials for Microphotonics , 2004 , L6.14
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Lin, B. X., Fu, Z. X., Jia, Y. B.., Appl. Phys. Lett. 79, 943 (2001).Google Scholar
2. Li, Q. H., Komarneni, S. and Roy, R., J. Mater. Sci. 30, 2358 (1995).Google Scholar
3. Che, C. M., Wan, C. W., Ho, K. Y., Zhou, Z.Y.., New. J. Chem. 25, 63 (2001).Google Scholar
4. Tao, J., Tong, M. L., Shi, J. X., Chen, X. M., Ng, S. W.., Chem. Commun. 20, 2043, (2000).Google Scholar
5. Rabenau, A., Angew Chem. Int. Ed. 24, 1017(1985)Google Scholar
6. Software packages SMART and SAINT, Siemens Analytical X-ray Instruments a) Inc., Madison, WI, (1996).Google Scholar
7. SHELXTL, version 5.1; Siemens Industrial Automation, Inc., (1997).Google Scholar
8. Sheldrick, G. M., “SADABS User's Guide.” University of Gottingen. (1995).Google Scholar
9. Bertoncello, R., Bettinelli, M., Cassrin, M., Gulino, A., Tondello, E. and Vittadini, A., Inorg. Chem. 31, 1558 (1992).Google Scholar