Hostname: page-component-84b7d79bbc-g78kv Total loading time: 0 Render date: 2024-08-01T22:26:47.323Z Has data issue: false hasContentIssue false

Valence Instability and Magnetic Polarization of Ce Atoms near the Interface of Ce/Fe Multilayers Studied by Magnetic Circular X-Ray Dichroism.

Published online by Cambridge University Press:  03 September 2012

F. Klose
Affiliation:
I. Physikalisches Institut, Universität Gottingen, Bunsenstr. 9. 3400 Gottingen, Germany
S. Pizzini
Affiliation:
LURE. Bâtiment 209D, Université Paris-Sud, 91405 Orsay, France
C. Giorgetti
Affiliation:
LURE. Bâtiment 209D, Université Paris-Sud, 91405 Orsay, France
O. Schulte
Affiliation:
LURE. Bâtiment 209D, Université Paris-Sud, 91405 Orsay, France
F. Baudelet
Affiliation:
LURE. Bâtiment 209D, Université Paris-Sud, 91405 Orsay, France
E. Dartyge
Affiliation:
LURE. Bâtiment 209D, Université Paris-Sud, 91405 Orsay, France
G. Krill
Affiliation:
LURE. Bâtiment 209D, Université Paris-Sud, 91405 Orsay, France
W. Felsch
Affiliation:
I. Physikalisches Institut, Universität Gottingen, Bunsenstr. 9. 3400 Gottingen, Germany
A. Fontaine
Affiliation:
LURE. Bâtiment 209D, Université Paris-Sud, 91405 Orsay, France
Get access

Abstract

An experimental study of conventional x-ray absorption and of magnetic circular x-ray dichroism has been performed on Ce/Fe Multilayers at the Ce L2,3 and the Fe-K edge, to characterize the impact of the interaction of Ce and Fe on the local electronic and magnetic structure of the interface. The spectra reveal that the interaction has two effects. First, on a depth scale of up to 15 A near the interface, the Ce atoms adopt the electronic structure of the oc-phase, with itinerant 4f states. Second, a large portion (=10 Å) of these cc-like Ce atoms is magnetically polarized and carries an ordered Magnetic 5d Moment. The Fe-3d and Ce-5d Moments are antiferromagnetically coupled. Interface Mixing on a length scale of the magnetic polarization can be excluded.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Eriksson, O., Nordstrom, L., Brooks, M.S.S., and Johansson, B., Phys. Rev. Lett. 60, 2523 (1988).Google Scholar
[2] Thiele, J., Klose, F., Schurian, A., Schulte, O., Felsch, W., and Bremen, O., J. Magn. Magn. Mater. 119, 141 (1993)Google Scholar
[3] see: Handbook on the Physics and Chemistry of Rare Earths, edited by Gschneidner, K. A., Eyring, L., and Hufner, S., Vol. 10, (North Holland, Amsterdam, 1987)Google Scholar
[4] Malterre, D., Phys. Rev. B 43, 1391 (1991)Google Scholar
[5] Fano, U., Phys. Rev. 178, 131 (1969); 184, 250 (1969)Google Scholar
[6] van der Laan, G., Phys. Rev. Lett. 66, 2527 (1991); J. Phys. Condens. Matter 3, 1015 (1991)Google Scholar
Thole, B. T. and van der Laan, G., Phys. Rev. Lett 67, 3306 (1991)Google Scholar
[7] Baudelet, F., Dartyge, E., Fontaine, A., Brouder, C., Krill, G., Kappler, J. P., and Piecuch, M., Phys. Rev. B 43, 5857 (1991)Google Scholar
[8] Riiegg, S., Schütz, G., Fischer, P., and Wienke, R., J. Appl. Phys. 69, 5655 (1991)Google Scholar
[9] Wu, Y., Stohr, J., Hermsmeier, B. D., Samant, M. G., and Weller, D., Phys. Rev. Lett. 69, 2307 (1992)Google Scholar
[10] Pizzini, S. et al., MRS Spring Meeting, San Francisco 1993 (This conference Symposium Ql)Google Scholar
[11] Tobin, J. G., Waddill, G. D., and Pappas, D. P., Phys. Rev. Lett. 68, 3642 (1992)Google Scholar
[12] Brouder, C. and Hikam, M., Phys. Rev. B 43, 3809 (1991)Google Scholar
[13] Giorgetti, C., Pizzini, s., Dartyge, E., Fontaine, A., Baudelet, F., Brouder, C., Krill, G., and Kappler, J. P., submitted to Phys. Rev. BGoogle Scholar
[14] Klose, F., Steins, M., Kacsich, T., and Felsch, W., J. Appl. Phys., in press.Google Scholar
[15] Bauer, P. (private communication)Google Scholar
[16] Baudelet, F., Brouder, C., Dartyge, E., Fontaine, A., Kappler, J. P., and Krill, G., Europhys. Lett. 13, 751 (1990)Google Scholar
[17] The γ-to-α phase transition in Ce Metal is connected with a 17 % decrease of the atomic volume (Gschneidner, K. A. Jr, Buletin of Alloy Phase Diagrams 11, 216 (1990)Google Scholar
[18] The only compounds are CeFe2 and Ce2Fe17; in addition, amorphous alloys exist.Google Scholar
[19] Vescovo, E., Rochów, R., Kachel, T., and Carbone, C., Phys. Rev. B 46, 4788 (1992)Google Scholar