Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-19T10:52:56.016Z Has data issue: false hasContentIssue false
  • English
  • Français

Controlled Nucleation and Growth in the Hydrothermal-Electrochemical Formation of BaTiO3 Films

Published online by Cambridge University Press:  15 February 2011

I. Escobar ,
C. Silva ,
J. Lorca ,
V. M. Fuenzalida ,
Judit. G. Lisoni  and
T. Vargas
I. Escobar
Affiliation:
Chilean Nuclear Energy Commission, car- ilva@reina.lreina.cchen.cl
C. Silva
Affiliation:
Chilean Nuclear Energy Commission, car- ilva@reina.lreina.cchen.cl
J. Lorca
Affiliation:
Chilean Nuclear Energy Commission, car- ilva@reina.lreina.cchen.cl
V. M. Fuenzalida
Affiliation:
U. Chile, FCFM, Dept. Physics, Casilla. 487-3, Stgo. Chile, vfuenzal@cec.uchile.cl
Judit. G. Lisoni
Affiliation:
U. Chile, FCFM, Dept. Physics, Casilla. 487-3, Stgo. Chile, vfuenzal@cec.uchile.cl
T. Vargas
Affiliation:
U. Chile, FCFM, Dept. Chem. Eng., Casilla. 2777-3, Stgo. Chile
Get access

Abstract

The influence of controlled potential conditions on the structure and phases of BaTiO3 films grown on titanium by the hydrothermal-electrochemical method was studied. The experiments were conducted using a three electrode high pressure electrochemical cell in a 0.2 M Ba(OH)2 electrolyte at 150 °C. The spontaneous initial nucleation linked to pure hydrothermal BaTiO3 formation was inhibited by cathodically protecting the titanium electrode since its immersion in the electrolyte. The application of initial nucleation pulses of varying cathodic potentials affected the grain size of the deposit. The growth of tetragonal BaTiO3 was achieved combining the initial inhibition of the pure hydrothermal growth, followed by nucleation under controlled potentiostatic conditions.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 403: Symposium I – Polycrystalline Thin Films: Structure, Texture, Properties and Applications II , 1995 , 101
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Yoshimura, M., Yoo, S.E., , Hayasi, M., and, Ishizawa, N., Jpn. J. Appl. Phys. 28[11], L2007 (1989); Report of the Research Laboratory of Engineering Materials, Tokyo Institute of Technology, 16, 9–14 (1991)Google Scholar
2. Kajiyosi, K., Ishizawa, N. and Yoshimura, M., J. Am. Ceram. Soc. 74[2], 369 (1991)Google Scholar
3. Cho, C.R., Jang, M.S., Jeong, S.Y., Lee, S.J., and Lim, B.M., Materials Letters 23, 203 (1995)Google Scholar
4. Diaz, H., Silva, C., Pilleux, M.E., Fuenzalida, V.M., and Vargas, T., presented at the International Society of Electrochemistry (ISE) Annual Meeting, Berlin, 5–10 (1993), Paper 11.2.44 (unpublished); submitted to the J. Am. Ceram. Soc.Google Scholar