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Crystal Chemistry and Electronic Structure of Magnesium based Mackay Icosahedron Type Approximants

Published online by Cambridge University Press:  01 February 2011

Julien Pierre Amelie Makongo
Affiliation:
Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Str. 40, 01187 Dresden, Germany
Yuri Moguilnikov
Affiliation:
Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Str. 40, 01187 Dresden, Germany
Christian Kudla
Affiliation:
Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Str. 40, 01187 Dresden, Germany
Daniel Grüner
Affiliation:
Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Str. 40, 01187 Dresden, Germany
Melanie Schäpers
Affiliation:
Fortis GmbH, Stockumer Str. 28, 58453 Witten, Germany
Guido Kreinery
Affiliation:
Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Str. 40, 01187 Dresden, Germany
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Abstract

In order to obtain reliable experimental information on the long-range order, the role of the valence electron concentration and the type of disorder for Mackay icosahedron type quasicrystals we have studied binary and ternary Mg based approximant phases. An overview is presented on the crystal structures, homogeneity ranges, physical properties, and electronic structures of the following intermetallic phases: Mg6Pd, Mg57Pd13, Mg56.4Pd13.5, Mg306Pd77, Mg3Pd, Mg5Pd2, Mg2Pd, Ga30-xMg32+xPd21-y, Ga15-x-yMg38+yPd13+x, GaMg3Pd2, Ag17Mg54, Ag7Mg26, and AgMg4.

Type
Research Article
Copyright
Copyright © Materials Research Society 2004

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References

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