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General Overview of Vibrational Spectroscopy of Layered Transition-Metal Oxides

Published online by Cambridge University Press:  10 February 2011

C. Julien  and
G.A. Nazri
C. Julien
Affiliation:
Laboratoire des Milieux Désordonnés et Hétérogènes, UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, 75252 Paris 05, France
G.A. Nazri
Affiliation:
Physics and Physical Chemistry Department, RCEL, General Motors R&D Center, Warren, MI 48090
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Abstract

We report the vibrational spectra of various layered transition-metal oxides, which are potential cathode materials for advanced Li-ion batteries. They provide high specific energy density, high voltage, and remarkable reversibility for lithium intercalation-deintercalation process. Studies were carried out by Raman and FTIR spectroscopies. Oxides such as LiMO2 (M=Co, Ni, Cr) layered compounds and their mixed compounds have been investigated. The local environment of cations against oxygen neighboring atoms has been determined by considering polyhedral units building the lattice. Structural modifications induced by intercalation-deintercalation process, by cation substitution, or by low-temperature preparation route are examined.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 548: Symposia EE – Solid State Ionics V , 1998 , 79
Copyright
Copyright © Materials Research Society 1999

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