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Heteroaromatics: Exceptional Materials for Second Order Nonlinear Optical Applications

Published online by Cambridge University Press:  25 February 2011

Alex K-Y. Jen ,
K. Y. Wong ,
V. Pushkara Rao ,
K. Drost  and
R. M. Mininni
Alex K-Y. Jen
Affiliation:
Eni Chem America Inc., Research and Development Center, 2000 Cornwall Road, Monmouth Junction, New Jersey 08852
K. Y. Wong
Affiliation:
Eni Chem America Inc., Research and Development Center, 2000 Cornwall Road, Monmouth Junction, New Jersey 08852
V. Pushkara Rao
Affiliation:
Eni Chem America Inc., Research and Development Center, 2000 Cornwall Road, Monmouth Junction, New Jersey 08852
K. Drost
Affiliation:
Eni Chem America Inc., Research and Development Center, 2000 Cornwall Road, Monmouth Junction, New Jersey 08852
R. M. Mininni
Affiliation:
Eni Chem America Inc., Research and Development Center, 2000 Cornwall Road, Monmouth Junction, New Jersey 08852
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Abstract

New classes of nonlinear optical molecules were synthesized and characterized. It is shown experimentally that molecules with heteroaromatic π-electron systems exhibit exceptional second order nonlinear optical response and good solubility. Measurement of the nonlinear optical properties of molecules containing heteroaromatic moieties with different length scale reveals a power law dependence of Bμ on the number of π-electrons. Also, the effects of two nitro groups as electron acceptors on the aromatic ring are discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 247: Symposium N – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1992 , 59
Copyright
Copyright © Materials Research Society 1992

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References

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