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Oxygen-Generating Gel Systems Induced by Visible Light and Application to Artificial Photosynthesis

Published online by Cambridge University Press:  17 January 2012

Kosuke Okeyoshi  and
Ryo Yoshida
Kosuke Okeyoshi
Affiliation:
RIKEN Advanced Science Institute Department of Materials Engineering, Graduate School of Engineering, The University of Tokyo
Ryo Yoshida
Affiliation:
Department of Materials Engineering, Graduate School of Engineering, The University of Tokyo
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Abstract

Toward complete artificial photosynthesis systems to generate hydrogen and oxygen using visible light and water, we firstly design and fabricate oxygen-generating gel systems using the electrostatic interactions of ionic functional groups and steric effects of a polymer network. By using a graft polymer chain with Ru(bpy)32+ units as sensitizers to closely arrange RuO2 nanoparticles as catalyst, the functional groups transmit multiple electrons cooperatively to generate oxygen. In this study, a novel strategy is shown to design a hierarchical network structure using colloidal nanoparticles and macromonomers.

Keywords

biomimetic (chemical reaction)photochemicalpolymer
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1418: Symposium LL/MM – Gels and Biomedical Materials , 2012 , mrsf11-1418-ll01-04
Copyright
Copyright © Materials Research Society 2012

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References

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