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Platinum Clusters with Phosphide Ligands: Synthesis and Characterization

Published online by Cambridge University Press:  15 February 2011

Ilya I. Moiseev ,
N. Yu. Kozitsyna ,
D. I. Kochubey  and
K. I. Zamaraev
Ilya I. Moiseev
Affiliation:
Institute of General & Inorganic Chemistry, Russian Academy of Sciences, Moscow
N. Yu. Kozitsyna
Affiliation:
Institute of General & Inorganic Chemistry, Russian Academy of Sciences, Moscow
D. I. Kochubey
Affiliation:
Institute of Catalysis, Russian Academy of Sciences, 630090 Novosibirsk
K. I. Zamaraev
Affiliation:
Institute of Catalysis, Russian Academy of Sciences, 630090 Novosibirsk
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Extract

Reduction of triphenylphosphine-containing Pt(II) complexes with H2, HCOOH and Na-amalgam was studied to compare the results with those for similar reductions of analogous Pd(II) complexes. Clusters of compositions [Pt(PPh2)]n, n=6–10, have been found to be the products of the reduction reactions under consideration.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 272: Symposium O – Chemical Processes in Inorganic Materials: Metal and Semiconductor Clusters , 1992 , 91
Copyright
Copyright © Materials Research Society 1992

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References

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