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Preparation, Characterization and Electrochemical Property of ZnCl2-doped Carbon Nanometer Material as the Anode of Lithium-ion Battery

Published online by Cambridge University Press:  03 September 2012

D.F. Zhou ,
Y.L. Zhao ,
Y.G. Chen ,
X.Y. Zhang  and
R.S. Wang
D.F. Zhou
Affiliation:
Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China School of Biological Engineering, Changchun University of Technology, Changchun 130012, China
Y.L. Zhao
Affiliation:
Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China
Y.G. Chen
Affiliation:
Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China
X.Y. Zhang
Affiliation:
Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China
R.S. Wang
Affiliation:
Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China
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Abstract

Phenolic resin-based nanoscopic carbonaceous materials have been prepared by doping different proportions of ZnCl2 into phenolic resin (PR) precursor at various heat-treatment temperatures and characterized by means of Brunner-Emmett-Teller method (BET), X-ray diffraction (XRD), transmission electron microscopy (TEM) and Raman spectroscopy analyses. The results show that as the ratio of PR to ZnCl2 is 1:3, the average size of grains and apertures are about from 40 to 60 nm and 3.86 nm, respectively, reaching nanometer level. When this material is used as electrode material of lithium ion battery, the reversible capacity the battery could be kept at 370 mA•h•g−1 after 10 charge/discharge cycles.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 822: Symposium S – Nanostructured Materials in Alternative Energy Devices , 2004 , S3.4
Copyright
Copyright © Materials Research Society 2004

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