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Stable Ti/TaSi2/Pt Ohmic Contacts on N-Type 6H-SiC Epilayer at 600°C in Air

Published online by Cambridge University Press:  15 March 2011

Robert S. Okojie
Affiliation:
NASA Glenn Research Center, Instrumentation and Controls Division 21000 Brookpark Road, M/S 77-1, Cleveland OH 44135; (216) 433-6522
David Spry
Affiliation:
Akima Corporation, Fairview Park, OH 44126.
Jeff Krotine
Affiliation:
Akima Corporation, Fairview Park, OH 44126.
Carl Salupo
Affiliation:
Akima Corporation, Fairview Park, OH 44126.
Donald R. Wheeler
Affiliation:
NASA Glenn Research Center, Instrumentation and Controls Division 21000 Brookpark Road, M/S 77-1, Cleveland OH 44135; (216) 433-6522
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Abstract

We report preliminary electrical and diffusion barrier characteristics of Ti (100nm)/TaSi2 (200nm)/Pt (300nm) thermally stable ohmic contact metallization on n-type 6H-SiC epilayers. These contacts exhibited linear ohmic characteristics with contact resistance in the range of (0.3×10−4−8×10−4) Δcm2 on n-type epilayer doped between 0.6 to 2×1019cm−3. The I-V characteristics and contact resistance remained stable after heat treatments at 500°C and 600°C in air for over 600 hours and 150 hours, respectively. Auger Electron Spectroscopy (AES) was used to analyze the metal and semiconductor interfaces to understand the prevailing reactions. The thermal stability of the ohmic contact between 500°C and 600°C in air is believed to be due to the formation of silicides and carbides of titanium after being annealed at 600°C in H2 (5%)/N2 forming gas for 30 minutes. The oxidation of silicon species that migrated after TaSi2 decomposition is proposed as the diffusion barrier mechanism.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

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References

REFERENCES

1. Bromstead, J.R., Weir, G.B., Johnson, R.W., Jaeger, R.C., and Baumann, E.D., Proc.1st Intl. High Temp. Elec. Conf., p. 2735, (1991).Google Scholar
2. Lee, R., Trombley, G., Johnson, B., Reston, R., Havasy, C., Mah, M., and Ito, C., Proc. 2nd Intl. High Temp. Elec. Conf., p. V38, (1994)Google Scholar
3. Passow, C., Gingerich, B., and Swenson, G., Proc. 4th Intl. High Temp. Elec. Conf., p. 219221, (1998).Google Scholar
4. Palmour, J.W., Kong, H.S., Waltz, D.G., Edmond, J.A., and Carter, C.H. Jr., Proc. 1st Intl. High Temp. Elec. Conf., p.511, (1991).Google Scholar
5. Jurgens, R.F., IEEE Trans. on Industrial Electronics, 1E–29, (2), p. 107111, (1982).Google Scholar
6. Shor, J.S., Weber, R.A., Provost, L.G., Goldstein, D., and Kurtz, A.D., J. Electrochemical Soc., 141 (2), p. 579581 (1994).Google Scholar
7. Liu, S., Reinhardt, K., Severt, C., Scofield, J., Ramalingam, M., and Tunstall, C., Sr., Proc. 3rd Intl. High Temp. Elec. Conf., p. VII (9-13), (1996).Google Scholar
8. Papanicolaou, N.A., Edwards, A.E., Rao, M.V., Wickenden, A.E., Koleske, D.D., Henry, R.L., and Anderson, W.T., Proc. 4th Intl. High Temp. Elec. Conf., p. 122127 (1998).Google Scholar
9. Cree Research, Durham, NC.Google Scholar
10. Okojie, R.S., Ned, A.A., Kurtz, A.D., and Carr, W.N., IEEE Trans. Electron Devices, 46 (2), pp. 269274 (1999).Google Scholar
11. Kuphal, E., Solid State Electronics, 24, pp. 6978, (1981).Google Scholar
12. Bellina, J.J. Jr., Zeller, M.V., in Novel Refractory Semiconductors, edited by Emin, D., Aselage, T.L., and Wood, C. (Mater. Res. Soc. Symp. Proc. 97, Pittsburgh, PA, 1987), p. 265.Google Scholar
13. Chamberlain, M.B., Thin Solid Films, 72, 305311 (1980).Google Scholar
14. Henisch, H.K., Semiconductor Contacts: An approach to ideas and models, International Series of Monographs on physics no. 70. (Clarendon Press, Oxford, 1984).Google Scholar
15. Murarka, S.P., J. Vac. Sci. Technol., 17, (4), Jul./Aug., p. 775792 (1988).Google Scholar
16. Lie, L.N., Tiller, W.A., and Saraswat, K.C., J. Appl. Phys., 56, (7), p. 21272132 (1984).Google Scholar
17. Razouk, R.R., Thomas, M.E., and Pressaco, S.L., J. Appl. Phys., 53, (7), p. 53425344 (1982).Google Scholar