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Surface-Induced Recrystallization of Amorphous Calcium Carbonates to Oriented Calcite Crystals

Published online by Cambridge University Press:  01 February 2011

T. Yong-Jin Han  and
Joanna Aizenberg
T. Yong-Jin Han
Affiliation:
Bell Laboratories, Lucent Technologies 600 Mountain Ave, Murray Hill, NJ 07974
Joanna Aizenberg
Affiliation:
Bell Laboratories, Lucent Technologies 600 Mountain Ave, Murray Hill, NJ 07974
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Abstract

Enigmatic functions of amorphous calcium carbonates (ACC) are explored by inducing the formation and the stabilization of spherulitic ACC particles on self-assembled monolayers (SAM) of hydroxy-terminated alkanethiols on Au surface. We demonstrate that the stabilized ACC particles can be induced to crystallize on command to form oriented calcite crystals by introducing a nucleating surface by a means of a secondary SAM surface with carboxylate functionality.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 873: Symposium K – Biological and Bio-Inspired Materials and Devices , 2005 , K4.10
Copyright
Copyright © Materials Research Society 2005

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