Hostname: page-component-848d4c4894-r5zm4 Total loading time: 0 Render date: 2024-06-26T20:37:20.518Z Has data issue: false hasContentIssue false

Tetraheterafulvalenes as Precursors of Conducting Materials

Published online by Cambridge University Press:  25 February 2011

George C. Papavassiliou*
Affiliation:
Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48, Vassileos Constantinou Ave., Athens 116/35 Greece
Get access

Abstract

Methods for preparation of thetraheterafulvalenes containig O, S, Se, N as additional he-teroatoms and some of their conducting products are described. Also, results concerning stoichi-ometry, structures, and physical properteis are briefly discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Papavassiliou, G. C., in Procc. of NATO-ASI on “Lower Dim. Systems and Mol. Electronics” Spetses, Greece, Aug. 1989, edited by Metzger, R. M. et al, (Plenum, New York) B248, 143 (1990).Google Scholar
[2] Papavassiliou, G. C. et al, Mol. Cryst. Liq. Cryst. 181, 171 (1990).Google Scholar
[3] Papavassiliou, G. C., Pure Appl. Chem., 62, 483 (1990).Google Scholar
[4] Papavassiliou, G. C. et al, in “Organic Superconductivity”, edited by Kresin, V.Z. and Xittle, W.A. (Plenum, New York, 1990), p. 367.Google Scholar
[5] Papavassiliou, G. C. et al, in “The Physics and Chemistry of Organic Superconductors” edited by Saito, G. and Kagoshima, S. (Springer-Verlag, Belrin, 1990), p. 247.Google Scholar
[6] Hountas, A. et al, Acta Cryst., C46, 224 ( 1990).Google Scholar
[7] Delhaes, P. et al, J. Physique (Fr.), 51, 1179 (1990).Google Scholar
[8] Terzis, A. et al, Synth. Metals, 42, 1715 (1991).Google Scholar
[9] Ducasse, L. et al. Synth. Metals, 42, 2483 (1991);Google Scholar
Biberacher, W. et al, Synth. Metals, 42, 2374 (1991).Google Scholar
[10] Papavassiliou, G. C., Synth. Metals, 42, 2535 (1991).Google Scholar
[11] Papavassiliou, G. C. et al, Z. Naturforsch. 45b, 1216 (1990).Google Scholar
[12] Papavassiliou, G. C., Kakoussis, V. C., and Lagouvardos, D. J., Naturforsch, Z., 46b‥. (1991); G. C. Papavassiliou, unpublished.Google Scholar
[13] Papavassiliou, G. C., Lagouvardos, D. J. and Kakoussis, V. C., Z. Naturforsch., in press; G. C. Papavassiliou, Synth. Metals, to be published.Google Scholar
[14] Papavassiliou, G. C. et al, these proceedings; G. C. Papavassiliou et al to be published.Google Scholar
[15] Refs. cited in [1, 2] herein, not referenced individually due to the space restrictions.Google Scholar
[16] Zambounis, J. S. and Mayer, C. W., Tetrah. Lett., 52, 2737 ( 1991).Google Scholar
[17] Papavassiliou, G. C, unpublished.Google Scholar
[18] Bailey, A. B., McCullough, R. D., Mays, M. D., Cowan, D. O., and Lerstrup, K. A., Synth. Metals, 27, B425 (1988);Google Scholar
Safier, O. G., Nazarov, D.V., Zorin, V.V., Rathmarkulov, D.L., Khim. Geterotskikl. Soedin, (6) 852 (1988).Google Scholar
[19] Dedik, S. G., Orlov, V. D., Edzhinya, A. S., Khodorkorskii, Cu. V., and Neiland, O., Khim. Geterotsikl. Soedin, (10) 1421 (1989);Google Scholar
Maigrat, N., Ricard, L., Charrier, C., Mathey, F., Angew. Chem. Int. Ed., Engl. 27, 950 (1988).Google Scholar
[20] Papavassiliou, G. C. et al, to be published: (la′-9c) (mp=210 °C) prepared according to Scheme 2 gave conducting salts.Google Scholar
[21] Preliminary studies of conducting crystals based on M(dmit)2 and selenium analogs [2] as well as on M(dcit)2 have been reported by the author and his coworkers (see refs. 61–65, 83, 86 cited in ref.fl]1] herein). Since then, several research groups have studied materials based on M(dmit)2.Google Scholar
[22] Vandevyner, M. et al, J. Phys. Chem., 95, 246 (1991);Google Scholar
Papavassiliou, G. C. et al, Chem. Scripta 29, 71 (1989).Google Scholar
[23] Some ethylenedioxy-tetrachalcogenafulvalenes were found to be more volatile than the ethylenedithio and ethylenediseleno- analogs and can be easily deposited; G.C. Papavassiliou, unpublished.Google Scholar
[24] Delhaes, P. and G.C. Papavassiliou, unpublished.Google Scholar
[25] Zambounis, J. S., et al, to be published in Adv. Mat., and these proceedings.Google Scholar
[26] Kikuchi, K. et al to be published; J. S. Zambounis et al to be published.Google Scholar
[27] Nigrey, P. J. et al, Synth. Metals, 27B., 481 (1988);Google Scholar
Hsu, S. -Y. and Chiang, L. Y., Synth. Metals 27B, 651 (1988);Google Scholar
Wang, H. H. et al, Chem. Mat. 1, 140 (1990).Google Scholar
[28] Nogami, T. et al in “The Physics and Chemistry of Organic Superconductors” edited by Saito, G. and Kagoshima, S. (Springer-Verlag, Belrin, 1990), p. 373.Google Scholar
[29] Yagubski, E. B. and Shibaeva, R., J. Mol. Str. 5, 25 (1989).Google Scholar
[30] Lagouvardos, D. J. and Papavassiliou, G. C., compounds based on (9), (11) are reported, to be published in Z.Naturforsch.Google Scholar