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Wetting Of Ion Containg Polymers: Micelles Versus Molecular Absorption

Published online by Cambridge University Press:  10 February 2011

T. A. Hill ,
X. Jiao ,
C. W. Martin ,
D. D. Demarteau  and
D. Perahia
T. A. Hill
Affiliation:
Chemistry Department, Clemson University, Clemson SC 29634-1905
X. Jiao
Affiliation:
Chemistry Department, Clemson University, Clemson SC 29634-1905
C. W. Martin
Affiliation:
Chemistry Department, Clemson University, Clemson SC 29634-1905
D. D. Demarteau
Affiliation:
Chemistry Department, Clemson University, Clemson SC 29634-1905
D. Perahia*
Affiliation:
Chemistry Department, Clemson University, Clemson SC 29634-1905
*
*Author for correspondence.
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Abstract

The wetting behavior of perfluorinated ionomers has been investigated as a function of polymer-surface interaction, the nature of the counter-ion and the structure of the polymer in the solvent from which it has been cast onto the surface. Two different ion-containing polymers, with a per-fluoro-carbon backbone were studied. They differ in the chemical composition and the polarity of their side chains. AFM results together with neutron reflectivity, light scattering and surface tension measurements had shown that the structure of the polymer in the parent solution has a profound effect on the wetting properties as well as the surface structure of the polymers.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 543: Symposium W – Dynamics in Small Confining Systems IV , 1998 , 189
Copyright
Copyright © Materials Research Society 1999

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References

«1» Patel, S.,Tirrell, M., and Hadziioannou, G., Colloid Surf. 31,157,(1988); MRS Bulletin 21, No. 1 (1996); J. Klein, E. Kumacheva, D. Mahalu, D. Perahia, and L. J. Fetters, Nature, 370, 634, (1994); M. Murat, G. S. Grest, K. Kremer, Phys. Lett.. 42, 401 (1998).Google Scholar
«2» Perahia, D.,Weisler, D.,Satija, S. K.,Fetters, L. J.,Sinha, S. K., and Milner, S. T., Phys. Rev. Lett. 72, 100, 1994; Auroy, P.,Auvray, L., and L. L'eger, Macromolecules, 24, 5158, (1991).Google Scholar
«3» Ionomers. Synthesis, Structure, Properties and applications Edit: M. R. Tant, K. A. Mauritz and G. L. Wilkes, lackie Accademic & Professional, (1997).Google Scholar
«4» Reiter, G., PRL, 68,75,1992; Reiter, G.,Auroy, P.,Auvrey, L., Macromolecules, 29, 2150, (1996); Klein et. al. Macromolecules, 31, 422, (1998)Google Scholar
«5» Karim, Feng, A., Weiss, R. A.,Douglas, J. F. and Han, C., PRL, 31, 484, (1998)Google Scholar
«6» Zawdzinski, T. A. Jr, Gottesfeld, S.,Shoichet, S. and MACarthy, T. J., J. Appl. Elecrochem., 23, 86, (1993); C. R. Martin et al., J. Elecrtochem. Soc. 139, 1634, (1992)Google Scholar
«7» Smith, N. S., Martin, Charles W. and Creager, S. E., privet comunication.Google Scholar
«8» Li, J. Y.,Peiffer, D. G. and Chu, B., Marcomolecules, 26, 4006, (1993)Google Scholar
«9» Tsuchida, E., Pure Appl. Chem, A31 1, (1994)Google Scholar
«10» Yu, K. and Eisenberg, A., Macromolecules, 29, 6359, 1996; L. Zhang, and A Eisenberg, Science, 268, 1728, (1995)Google Scholar
«11» Orler, E. B.,Calhun, B. H. and Moore, R. B., Macromolecules, 29, 5965, (1996)Google Scholar
«12» Su, S. and Mauritz, K., Macromolecules, 27, 2079, (1994)Google Scholar
«13» Albert, P.,Dreyfus, B.,Gebel, G.,Nakamura, N.,Pineri, M., and Volino, F., Journal de-Physic-France, 49, 2101, (1988)Google Scholar
«14» Martin, C. W. et. al. in ACS Symp. Ser., edited by Ultracki, L.A. and Weiss, R. A. ( 395, 370,1989)Google Scholar
«15» Demarteau, D. D., J. Fluorine Chem., 72, 203, (1995); E. Tsuchida et. al. Macromolecules, 31, 403, (1998).Google Scholar
«16» Martin, C. W.,Gordon, T. D.,Baker, S. H., and Davila, M., “Forming thin, durable coatings of ion-containing polymers on selected substrates”, US 5,718,947 (1998).Google Scholar
«17» Perahia, D.,Hill, T. A. and Martin, C. W., DOE workshop on Fuel cells, April 1998 Las Vegas; Martin, C. W.,Hill, T. A., and Perahia, D., APS meeting 1998.Google Scholar