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X-Ray Powder Data for Two μ3-Oxo-Hexakis-(μ2-Carboxyl-atopyridine-O,O) triaquachromium(III) Perchlorates: {[Cr3O(C6H5NO2)6(H2O)3](ClO4)7· 3NaClO4· 0.5(C6H5NO2)· 3H2O} and {[Cr3O(C6H5NO2)6(H2O)3](ClO4)7 · 6NaClO4·3H2O}

Published online by Cambridge University Press:  19 May 2016

D.F. Mullica  and
J.E. Bradshaw
D.F. Mullica
Affiliation:
Chemistry and Physics Departments, Baylor University, Waco, Texas 76798, U.S.A.
J.E. Bradshaw
Affiliation:
Chemistry and Physics Departments, Baylor University, Waco, Texas 76798, U.S.A.
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Abstract

Indexed X-ray diffraction powder data for {[Cr3O(C6H5NO2)6(H2O)3](CIO4)7 · 3NaCIO4·0.5(C6H5NO2)· 3H2O}, INICCR (isonicotinato) and {[Cr3O(C6H5NO2)6(H2O)3] (CIO4)7·6NaCIO4·3H2O}, PICOCR (picolinato) are reported. Both INICCR and PICOCR crystallize in the hexagonal space group P63/m. Crystal data determined for INICCR are a = 13.838(3) Å, c = 25.038(8) Å, V = 4152.2 Å3, Dx = 1.71 Mg m−3 (Dm = 1.66(5) Mg m−3), F25 = 26.5(0.020,47) and for PICOCR are a = 13.966(4) Å, c = 24.518(6) Å, V = 4141.5 Å3, Dx = 1.96 Mg m−3 (Dm = 1.94(4) Mg m−3), F21 = 17.9(0.023,51). The JCPDS Diffraction File Number for INICCR is 38-1992 and for PICOCR is 38-1993.

Type
Research Article
Information
Powder Diffraction , Volume 3 , Issue 3 , September 1988 , pp. 177 - 178
Copyright
Copyright © International Centre for Diffraction Data 1988

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References

Bradshaw, J.E., Thesis, Baylor University, Waco, Texas (1987).Google Scholar
Bradshaw, J.E., Grossie, D.A., Mullica, D.F., and Pennington, D.E. (1988). Inorg. Chim. Acta 141, 41–47.CrossRefGoogle Scholar
De Wolff, P.M. (1968). J. Appl. Crystallogr., 1, 108–113.CrossRefGoogle Scholar
Haylock, S.J., Buckley, P.D., and Blackwell, L.F. (1983). J. Inorg. Biochem., 18, 195–211.CrossRefGoogle Scholar
Marquardt, D.W. (1963). J. Soc. Indust. Appl. Math., 11, 431–441.CrossRefGoogle Scholar
Mullica, D.F., Sappenfield, E.L., and Bradshaw, J.E. (1986). Powder Diffraction, 1(3), 261–262.CrossRefGoogle Scholar
Schwarz, K. and Mertz, W. (1957). Arch. Biochem. Biophys., 72, 515–518.CrossRefGoogle Scholar
Smith, G.S. and Snyder, R.L. (1979). J. Appl. Crystallogr., 23, 60–65.CrossRefGoogle Scholar