A mid-infrared high-resolution spectral survey of the source IRC+10216 (CW Leo) has been carried out between 11 and 14 $\mu$m. A large number of lines of C$_2$H$_2$ and HCN and their most abundant isotopologues, have been identified. Lines involving high-energy ro-vibrational levels allow an accurate derivation of the physical and chemical conditions in the innermost envelope. We have developed a radiative transfer model capable of fitting the observed lines satisfactorily. The fit of more than 200 ro-vibrational lines allowed us to get the kinetic, vibrational and rotational temperatures and the abundances of the C$_2$H$_2$ and HCN between 1 and 300 R$_*$.